Enhanced Catalytic Performance of UiO-67 Supported Pd Catalyst for Toluene Degradation

• Published in: Catalysis letters 2024-09, Vol.154 (9), p.5223-5235
• Main Authors: Zhao, Chunzhi, Mao, Dongsen, Meng, Tao, Guo, Qiangsheng, Yu, Jun
• Format: Article
• Language: English
• Subjects: Benzaldehyde; Benzoates; Catalysis; Catalysts; Chemistry; Chemistry and Materials Science; Industrial Chemistry/Chemical Engineering; Metal-organic frameworks; Nanoparticles; Organometallic Chemistry; Palladium; Performance degradation; Physical Chemistry; Stability; Toluene; Topology; Zirconium dioxide
• ISSN: 1011-372X; 1572-879X
• DOI: 10.1007/s10562-024-04712-z

Owing to the intrinsic nature of the uniformed topologies and ultrasmall Zr 6 nodes of Zr-MOFs, herein, we employed Zr-MOFs (UiO-66 and UiO-67), as opposed to the support of traditional ZrO 2 , to prepare the Pd catalysts for toluene degradation. Compared with the catalysts of Pd/UiO-66 and Pd/ZrO 2 , Pd/UiO-67 catalyst boosted an excellence catalytic performance for toluene degradation, giving the lowest T 90% value of 235 °C with long-term stability. With the assisting of the cavity confinement of Zr-MOFs, Pd nanoparticles are prone to be encapsulated in the 3D frameworks of Zr-MOFs, and the bigger micropores of UiO-67 are more conducive to the formation of larger Pd nanoparticles. The in situ FT-IR results further declared that although the active sites are partly sacrificed due to the larger Pd nanoparticles formed in UiO-67, the stable adsorbed toluene on Pd/UiO-67 boosted the quick degradation of toluene in the reaction interval even without undergoing intermediate processes of benzoate and benzaldehyde. Graphical Abstract UiO-66, UiO-67 and ZrO 2 were employed to prepare the Pd catalysts for toluene degradation, Pd/UiO-67 catalyst boosted an excellence catalytic performance with long-term stability.