Unveiling the photocatalytic potential of graphitic carbon nitride (g-CN): a state-of-the-art review

• Published in: RSC advances 2024-08, Vol.14 (35), p.25629-25662
• Main Authors: Ahmed, Mahmoud A, Mahmoud, Safwat A, Mohamed, Ashraf A
• Format: Article
• Language: English
• Subjects: Carbon; Carbon nitride; Catalysts; Catalytic activity; Chemistry; Clean energy; Heterojunctions; Hydrogen production; Parameter identification; Performance degradation; Photocatalysis; Photocatalysts; Photodegradation; Reaction mechanisms; State-of-the-art reviews; Structural analysis
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d4ra04234d

Graphitic carbon nitride (g-C 3 N 4 )-based materials have emerged as promising photocatalysts due to their unique band structure, excellent stability, and environmental friendliness. This review provides a comprehensive and in-depth analysis of the current state of research on g-C 3 N 4 -based photocatalysts. The review summarizes several strategies to improve the photocatalytic performance of pristine g-C 3 N 4 , e.g. , by creating heterojunctions, doping with non-metallic and metallic materials, co-catalyst loading, tuning catalyst morphology, metal deposition, and nitrogen-defect engineering. The review also highlights the various characterization techniques employed to elucidate the structural and physicochemical features of g-C 3 N 4 -based catalysts, as well as their applications of in photocatalytic degradation and hydrogen production, emphasizing their remarkable performance in pollutants' removal and clean energy generation. Furthermore, this review article investigates the effect of operational parameters on the catalytic activity and efficiency of g-C 3 N 4 -based catalysts, shedding light on the key factors that influence their performance. The review also provides insights into the photocatalytic pathways and reaction mechanisms involving g-C 3 N 4 based photocatalysts. The review also identifies the research gaps and challenges in the field and presents prospects for the development and utilization of g-C 3 N 4 -based photocatalysts. Overall, this comprehensive review provides valuable insights into the synthesis, characterization, applications, and prospects of g-C 3 N 4 -based photocatalysts, offering guidance for future research and technological advancements in this rapidly growing field. Graphitic carbon nitride (g-C 3 N 4 )-based materials have emerged as promising photocatalysts due to their unique band structure, excellent stability, and environmental friendliness.