Spark Plasma Sintering of Al2O3–SiC Ceramics. Study of the Microstructure and Properties

• Published in: Technical physics 2024-02, Vol.69 (2), p.148-159
• Main Authors: Boldin, M. S., Popov, A. A., Murashov, A. A., Sakharov, N. V., Shotin, S. V., Nokhrin, A. V., Chuvil’deev, V. N., Smetanina, K. E., Tabachkova, N. Yu
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Ceramics; Classical and Continuum Physics; Diffusion rate; Grain boundary diffusion; Hardness; Heating; Microstructure; Nanoparticles; Physics; Physics and Astronomy; Plasma sintering; Silicon carbide; Sintering (powder metallurgy); Spark plasma sintering; Surface hardness; Temperature dependence
• ISSN: 1063-7842; 1090-6525
• DOI: 10.1134/S1063784224010055

The features of spark plasma sintering of submicron Al 2 O 3 powders with different contents (0, 0.5, 1.5, 5 vol %) of β-SiC nanoparticles have been studied. The microstructure and hardness of Al 2 O 3 + 5 vol % SiC ceramics obtained by sintering Al 2 O 3 powders with β-SiC particles of various types (nanoparticles, submicron particles, fibers) have been studied. Sintering was carried out at heating rates ( V h ) from 10 to 700°C/min. The sintering process of Al 2 O 3 + SiC ceramics with low heating rates ( V h = 10–50°C/min) has a complex three-stage character, with a flat area in the temperature range of 1200–1300°C. At high heating rates ( V h > 250°C/min), the usual three-stage character of sintering is observed. The analysis of temperature dependences of compaction was carried out using the Young–Cutler model; it was found that the kinetics of powder sintering is limited by the intensity of grain boundary diffusion. It is shown that the dependence of the hardness of Al 2 O 3 + SiC ceramics on V h has a nonmonotonic character, with a maximum. In the case of pure alumina, an increase in V h leads to a monotonic decrease in hardness.