Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L) 4 RuCl 2 ] 2+ and [Pd(μ-L) 4 Pt] 4+ cage architectures

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary pro...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-09, Vol.60 (78), p.10950-10953
Main Authors: Gearing, Hayden B, Söhnel, Tilo, Young, Paul, Lisboa, Lynn, Wright, L James, Crowley, James D, Hartinger, Christian G
Format: Article
Language:English
Subjects:
Binding
Bonding
Construction standards
Palladium
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Summary:Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc03613a