Corrosion Failure Mechanism of 2507 Duplex Stainless Steel Circulation Pump Impeller

• Published in: Processes 2024-09, Vol.12 (9), p.1897
• Main Authors: Wang, Weihua, Hou, Chengbao, Li, Jiaxing, Shi, Mingxiao, Chen, Jiugong, Qian, Gong
• Format: Article
• Language: English
• Subjects: Bubbles; Cathodes; Cavitation; Chemical composition; Chemical elements; Chloride ions; Circulation; Contact pressure; Corrosion; Corrosion cell; Corrosion effects; Corrosion mechanisms; Corrosion potential; Corrosion prevention; Corrosion products; Corrosion resistance; Corrosion tests; Corrosive wear; Crack initiation; Distillation; Duplex stainless steels; Erosion control; Failure analysis; Failure mechanisms; Galvanic corrosion; Impact loads; Impellers; Ions; Low pressure; Molybdenum; Morphology; Pits; Point defects; Pump impellers; Scanning electron microscopy; Spectrum analysis; Stainless steel; Steel; Water vapor
• ISSN: 2227-9717; 2227-9717
• DOI: 10.3390/pr12091897

The circulation pump in a distillation column is a core device in a material circulation system, and its stable operation is crucial for the production process. The impeller of the circulation pump is prone to failure due to long-term contact with corrosive media, and subjected to a large amount of material erosion, which severely challenges the safety control of the distillation reaction system. Focusing on the corrosion failure phenomenon of circulation pump impellers, the failure mechanism was studied by means of macroscopic inspection, chemical composition analysis, metallographic examination, scanning electron microscopy (SEM), and energy dispersive spectrometer (EDS). Results indicated that the corrosion of circulation pump impellers was the result of the combined effects of surface wear, cavitation, and halogen element corrosion. The medium in contact with the impeller contained chloride ions, fluoride ions, and solid particles. During circulation pump operation, a low-pressure zone formed at the inlet, generating numerous water vapor bubbles. These bubbles burst in the high-pressure zone, creating highly localized impact forces. Combined with the abrasive action of solid particles on the impeller surface, this led to the destruction of the passivation film and the formation of numerous small pits. These corrosion pits and the surrounding environment formed micro-galvanic corrosion cells with small anodes and large cathodes. Under the accelerated corrosion caused by fluoride and chloride ions, the corrosion process towards the inner wall of the impeller intensified, ultimately leading to impeller failure. This study clarified the corrosion failure mechanism and its root causes in the 2507 duplex stainless steel circulation pump impeller and proposes corresponding improvement recommendations, providing a scientific basis for preventing similar issues from occurring in the future.