The Peculiar Molecular [(IF5)6(HF2)4]4− Anion of the Compound K4[(IF5)6(HF2)4]

K4[(IF5)6(HF2)4] was obtained from the reaction of K[HF2] with liquid IF5. The compound was analyzed by single crystal and powder X‐ray diffraction, Raman spectroscopy, and quantum‐chemical calculations. It contains the largest molecular IF5/HF2− complex anion known so far. Surprisingly, the crystal...

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Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2024-09, Vol.650 (17), p.n/a
Main Authors: Koch, Björn N., Graubner, Tim, Kraus, Florian
Format: Article
Language:English
Subjects:
Anions
Crystal structure
hydrogen fluoride
interhalide
Iodine pentafluoride
Molecular structure
Raman spectroscopy
Single crystals
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Graubner, Tim
Kraus, Florian
description K4[(IF5)6(HF2)4] was obtained from the reaction of K[HF2] with liquid IF5. The compound was analyzed by single crystal and powder X‐ray diffraction, Raman spectroscopy, and quantum‐chemical calculations. It contains the largest molecular IF5/HF2− complex anion known so far. Surprisingly, the crystal structure of the A4B compound can be related to the Hg4Pt structure type.
doi_str_mv 10.1002/zaac.202400085
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subjects Anions
Crystal structure
hydrogen fluoride
interhalide
Iodine pentafluoride
Molecular structure
Raman spectroscopy
Single crystals
title The Peculiar Molecular [(IF5)6(HF2)4]4− Anion of the Compound K4[(IF5)6(HF2)4]
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