High‐Performance Microfluidic Techniques toward Nanostructuration of BODIPY and BOPHY Based CPPs Hybrid Photocatalyst for Hydrogen Production

• Published in: Advanced functional materials 2024-10, Vol.34 (40), p.n/a
• Main Authors: Palenzuela‐Rebella, Sandra, Naranjo, Teresa, Gomez‐Mendoza, Miguel, Barawi, Mariam, Liras, Marta, de la Peña O´Shea, Víctor A.
• Format: Article
• Language: English
• Subjects: artificial photosynthesis; Catalytic activity; Chemical synthesis; conjugated porous polymers; HPMT; hybrid photocatalyst; Hydrogen evolution reactions; Hydrogen production; Microfluidics; Nanostructure; Particle size; Photocatalysis; Photocatalysts; Photoluminescence; Polymer films; polymer nanoparticles; Polymers; Thin films; Titanium dioxide
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.202403778

Here, the use of high‐performance microfluidic techniques (HPMT) is reportedto afford conjugated porous polymer (CPPs) with smaller particle size and narrower particle size dispersion than the obtained by miniemulsion methodology. Specifically, polymers based on BODIPY or BOPHY dyes are synthesized by HPMT conditions and conventional miniemulsion conditions. The polymer textural properties from HPMT are notably improved, giving rise to high‐quality thin films that are photoelectrochemically characterized. Furthermore, hybrid materials of CPPs synthesized by HPMT and TiO2 inorganic semiconductor revealed enhanced photocatalytic activity in the hydrogen evolution reaction (HER). The most active hybrid UN_IEP‐7@T‐10 photocatalyst, containing 10 wt% polymer loading, achieved a hydrogen evolution rate of 3.10 mmol g−1 h−1 (ƺ = 1.13%), which is threefold higher than that of its non‐nanostructured from bulk synthesis, two‐times greater than its nanostructured by conventional miniemulsion techniques and even surpassed by 39‐times the performance of bare TiO2. It is noteworthy that both photoluminescence lifetime (τPL) and transient lifetime (τT) are not affected by the nanoestructuration of CPPs, which agrees with the preservation of the chemical structure by both synthetic methodologies. The employment of HPMT as nanostructuration strategy clearly supports the obtaining of more processable polymers for a wide range of energy applications. This work illustrates a new synthetic procedure for the nanostructuring of cCPPs) by the use of high‐performance microfluidic techniques. In this case, Ultra_Nano CPPs present smaller particle size and narrower particle size dispersion than the obtained by miniemulsion synthetic methodology. This is translated in more contact points when synthesizing hybrids thereof and TiO2, achieving enhanced photocatalytic activity in the hydrogen evolution reaction.