Insight into Fluoride Additives to Enhance Ammonia Production from Lithium‐Mediated Electrochemical Nitrogen Reduction Reaction (Small 40/2024)

Nitrogen Reduction Reaction Adding F‐additives with low lowest occupied molecular orbital energy during the electrochemical Li‐mediated N2 reduction reaction results in the formation of LiF solid electrolyte interphases. This process effectively reduces the energy barrier for the hydrogenation of Li...

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Bibliographic Details
Published in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-10, Vol.20 (40), p.n/a
Main Authors: Shin, Dongwoo, Jeon, Yeongbae, Nguyen, Vy Thuy, Kang, Shinmyeong, Hong, Yewon, Lim, Chaeeun, Yong, Kijung, Shin, Hyeyoung, Hwang, Yun Jeong
Format: Article
Language:English
Subjects:
Additives
Ammonia
ammonia synthesis
Chemical reduction
electrochemical nitrogen reductions
Lithium
lithium fluoride
lithium‐mediated nitrogen reduction
Molecular orbitals
solid electrolyte interphases
Solid electrolytes
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Summary:Nitrogen Reduction Reaction Adding F‐additives with low lowest occupied molecular orbital energy during the electrochemical Li‐mediated N2 reduction reaction results in the formation of LiF solid electrolyte interphases. This process effectively reduces the energy barrier for the hydrogenation of Li3N on the surface, thereby enhancing the efficient production of NH3. More in article number 2404525, Hyeyoung Shin, Yun Jeong Hwang, and co‐workers.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.202470299