Aggregation-induced emission-active supramolecular polymers: from controlled preparation to applications

• Published in: Chemical Society reviews 2024-10, Vol.53 (2), p.1189-1215
• Main Authors: Wang, Beibei, Liu, Yuhao, Chen, Xueqian, Liu, Xiao-Ting, Liu, Zhongyi, Lu, Chao
• Format: Article
• Language: English
• Subjects: Addition polymerization; Chemical bonds; Emission; Polymers; Supramolecular polymers
• ISSN: 0306-0012; 1460-4744; 1460-4744
• DOI: 10.1039/d3cs00017f

Supramolecular polymers are typical self-assemblies, in which repeating monomer units are bonded together with dynamic and reversible noncovalent interactions. Supramolecular polymers can combine the advantages of polymer science and supramolecular chemistry. Aggregation-induced emission (AIE) means that a molecule remains faintly emissive in the dispersed state but intensively luminescent in a highly aggregated state. AIE has brought new opportunities and further development potential to the field of polymeric chemistry. The integration of AIE luminogens with supramolecular interactions can provide new vitality for supramolecular polymers. Therefore, it is essential for scientists to understand the preparation and applications of AIE-active supramolecular polymers. This review focuses on the recent advanced progress in the preparation of AIE-active supramolecular polymers. In addition, we summarize the newly developed supramolecular polymers with an AIE nature and their applications in chemical sensing, and in vitro and in vivo imaging, as well as the visualization of their structure and properties. Finally, the development trends and challenges of AIE-active supramolecular polymers are prospected. This review focuses on the controlled preparation and applications of aggregation-induced emission (AIE)-active supramolecular polymers, aiming to inspire researchers in designing the next generation of novel AIE-active supramolecular polymers.