Advanced rubbery polymeric hydrogel for waste water remediation

• Published in: Polymer bulletin (Berlin, Germany) Germany), 2024-11, Vol.81 (17), p.15975-15993
• Main Author: Abou El Fadl, Faten Ismail
• Format: Article
• Language: English
• Subjects: Acrylamide; Adsorbents; Adsorption; Aqueous solutions; Cellulose; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Cobalt; Complex Fluids and Microfluidics; Composition effects; Controllability; Copolymerization; Crosslinking; Desorption; Equilibrium; Experiments; Gamma rays; Heavy metals; Hydrogels; Industrial applications; Latex; Mechanical properties; Natural rubber; Organic Chemistry; Original Paper; Physical Chemistry; Pollutants; Polymer Sciences; Polymers; Polyvinyl alcohol; Radiation; Radiation dosage; Soft and Granular Matter; Swelling; Temperature
• ISSN: 0170-0839; 1436-2449
• DOI: 10.1007/s00289-024-05452-1

This study displays the preparation and characterization of cross-linked rubbery hydrogel by applying gamma radiation as a fast and clean tool for industrial application. Rubbery Gel polymer was synthesized through radiation copolymerization between hydrophilic acrylamide (AAM) copolymerized with natural rubber latex at different monomer concentrations (80, 70, and 50% v/v) by using gamma radiation in order to prepare a cross-linked network between PAM and NRL (PAAM/NRL) with controllable hydrophilicity and good mechanical properties. The effect of AAM/NRL compositions and irradiation dose on the gel fraction, swelling isotherm and diffusional characteristics fully studied. The formed rubbery hydrogel with suitable swelling properties examined for the ability of adsorption of heavy metals from their aqueous solutions. Different parameters such as initial metal concentration, pH, temperature and adsorbent dosage are applied for the evaluation of the adsorption ability of the rubbery hydrogel for various toxic metals (Cu 2+ , Co 2+ , and Ni 2+ ). The results of metal uptake showed that increasing temperature has an effective impact on the metal uptake for various types of metals tested as increasing temperature increases the rubber chains flexibility within the PAAM/NRL rubbery hydrogel. The desorption of adsorbed metal ions from the PAAM/NRL hydrogel was completed in a desorption mediums of HCL (2 and 0.5 M) and at temperature of 70 °C after 90 min.