Photocatalytic degradation of malachite Green dye using Ti3C2 MXene nanosheets decorated with Fe3O4 NPs under visible light irradiation

• Published in: Research on chemical intermediates 2024-11, Vol.50 (11), p.5117-5135
• Main Authors: Alkhudaydi, Amal M., Danish, Ekram Y., Lima, Eder Claudio, Gabal, M.A., Salam, Mohamed Abdel
• Format: Article
• Language: English
• Subjects: Catalysis; Chemistry; Chemistry and Materials Science; Dyes; Electromagnetic absorption; Electrons; Fourier transforms; Infrared analysis; Inorganic Chemistry; Iron oxides; Light irradiation; Malachite green; MXenes; Nanocomposites; Nanoparticles; Optical properties; Particle size distribution; Photocatalysis; Photodegradation; Physical Chemistry; Scanning electron microscopy; Surface area; Transmission electron microscopy; Two dimensional analysis; Ultrasonic methods; Wastewater treatment; X-ray diffraction
• ISSN: 0922-6168; 1568-5675
• DOI: 10.1007/s11164-024-05415-1

In this research, a novel Fe 3 O 4 @Ti 3 C 2 MXene nanocomposite was prepared by a simple ultrasonic method by combining Ti 3 C 2 MXene and Fe 3 O 4 nanoparticles, and was used for the remediation of malachite green (MG) dye, as an example of an organic pollutant, from the environment through photocatalytic degradation under visible light irradiation. A wide variety of techniques were used to characterize the synthesized Fe 3 O 4 @Ti 3 C 2 MXene nanohybrid, including X-ray diffraction analysis (XRD), surface area analysis, scanning and transmission electron microscopy (SEM and TEM), and Fourier transform infrared spectroscopy (FTIR) in addition to the optical properties and band gap analysis. The results showed that the Ti 3 AlC 2 MAX phase’s Al layer was successfully selectively etched, resulting in the two-dimensional layered Ti 3 C 2 MXene (average diameter of 78 nm). Additionally, the results revealed the preparation of the cubic Fe 3 O 4 phase (average particle size of 11 nm), which was distributed homogeneously on the Ti 3 C 2 MXene surface, as indicated by XRD, SEM, and TEM analysis. Moreover, the Fe 3 O 4 @Ti 3 C 2 MXene nanophotocatalyst exhibits good visible light absorption ability under visible light (> 420 nm) due to its huge surface area, excellent conductivity, and sufficient quantity of active sites, and the accessibility of all elements required for effective photocatalysis. Accordingly, under 300 min of visible light exposure, the Fe 3 O 4 @Ti 3 C 2 MXene nanophotocatalyst successfully photodegraded MG dye more efficiently than the pure MXene with a removal percentage of 95.4% with 0.5 g/L loading. Overall, the current study has shown that the Fe 3 O 4 @Ti 3 C 2 MXene nanophotocatalyst has the potential to be a valuable photocatalyst for exceptionally efficient wastewater treatment applications.