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Enhanced Dielectric, Thermal, Energy Storage, Quality Factor, Impedance, and Conductivity Properties of Novel PVDF/PAN/ZrO2 Polymer Nanocomposites for Flexible Electronics Applications
ABSTRACT In this study, novel polymer nanocomposite films based on polyvinylidene fluoride/polyacrylonitrile/zirconium dioxide (PVDF/PAN/ZrO2) were prepared using a solution casting technique. The structural modifications and morphological properties were analyzed by x‐ray diffraction (XRD) and high...
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| Published in: | Polymers for advanced technologies 2024-10, Vol.35 (10), p.n/a |
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| container_title | Polymers for advanced technologies |
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| creator | Vilvanatha Prabu, A. Vijayaraghavan, G. V. Basheer Ahamed, M. Suganya, R. |
| description | ABSTRACT
In this study, novel polymer nanocomposite films based on polyvinylidene fluoride/polyacrylonitrile/zirconium dioxide (PVDF/PAN/ZrO2) were prepared using a solution casting technique. The structural modifications and morphological properties were analyzed by x‐ray diffraction (XRD) and high resolution scanning electron microscopy (HRSEM). The obtained results verified the filler‐polymer interactions and uniform dispersion of the ZrO2 filler in the host polymers (PVDF and PAN). Thermal stability of up to 46% leftover residue for 30% ZrO2 nano‐filler loading in the blend polymer nanocomposite was analyzed by thermogravimetric analysis (TGA). The dielectric properties such as dielectric constant and dielectric loss values and impedance, Q‐factor, and AC conductivity were analyzed using an impedance analyzer. The decrement in impedance with increasing nano‐filler content with improved dielectric, thermal, Q‐factor, energy density and conductivity properties signifies the prepared novel PVDF/PAN/ZrO2 polymer nanocomposite as an effective material for flexible electronics applications. |
| doi_str_mv | 10.1002/pat.6599 |
| format | article |
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In this study, novel polymer nanocomposite films based on polyvinylidene fluoride/polyacrylonitrile/zirconium dioxide (PVDF/PAN/ZrO2) were prepared using a solution casting technique. The structural modifications and morphological properties were analyzed by x‐ray diffraction (XRD) and high resolution scanning electron microscopy (HRSEM). The obtained results verified the filler‐polymer interactions and uniform dispersion of the ZrO2 filler in the host polymers (PVDF and PAN). Thermal stability of up to 46% leftover residue for 30% ZrO2 nano‐filler loading in the blend polymer nanocomposite was analyzed by thermogravimetric analysis (TGA). The dielectric properties such as dielectric constant and dielectric loss values and impedance, Q‐factor, and AC conductivity were analyzed using an impedance analyzer. The decrement in impedance with increasing nano‐filler content with improved dielectric, thermal, Q‐factor, energy density and conductivity properties signifies the prepared novel PVDF/PAN/ZrO2 polymer nanocomposite as an effective material for flexible electronics applications.</description><identifier>ISSN: 1042-7147</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.6599</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Dielectric loss ; Dielectric properties ; Electronics ; Fillers ; Flexible components ; flexible energy storage ; Impedance ; Nanocomposites ; PAN ; Polyacrylonitrile ; Polymer films ; Polymers ; Polyvinylidene fluorides ; PVDF ; Q‐factor ; Thermal stability ; Thermogravimetric analysis ; Zirconium dioxide</subject><ispartof>Polymers for advanced technologies, 2024-10, Vol.35 (10), p.n/a</ispartof><rights>2024 John Wiley & Sons Ltd.</rights><rights>2024 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-0460-7064</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Vilvanatha Prabu, A.</creatorcontrib><creatorcontrib>Vijayaraghavan, G. V.</creatorcontrib><creatorcontrib>Basheer Ahamed, M.</creatorcontrib><creatorcontrib>Suganya, R.</creatorcontrib><title>Enhanced Dielectric, Thermal, Energy Storage, Quality Factor, Impedance, and Conductivity Properties of Novel PVDF/PAN/ZrO2 Polymer Nanocomposites for Flexible Electronics Applications</title><title>Polymers for advanced technologies</title><description>ABSTRACT
In this study, novel polymer nanocomposite films based on polyvinylidene fluoride/polyacrylonitrile/zirconium dioxide (PVDF/PAN/ZrO2) were prepared using a solution casting technique. The structural modifications and morphological properties were analyzed by x‐ray diffraction (XRD) and high resolution scanning electron microscopy (HRSEM). The obtained results verified the filler‐polymer interactions and uniform dispersion of the ZrO2 filler in the host polymers (PVDF and PAN). Thermal stability of up to 46% leftover residue for 30% ZrO2 nano‐filler loading in the blend polymer nanocomposite was analyzed by thermogravimetric analysis (TGA). The dielectric properties such as dielectric constant and dielectric loss values and impedance, Q‐factor, and AC conductivity were analyzed using an impedance analyzer. The decrement in impedance with increasing nano‐filler content with improved dielectric, thermal, Q‐factor, energy density and conductivity properties signifies the prepared novel PVDF/PAN/ZrO2 polymer nanocomposite as an effective material for flexible electronics applications.</description><subject>Dielectric loss</subject><subject>Dielectric properties</subject><subject>Electronics</subject><subject>Fillers</subject><subject>Flexible components</subject><subject>flexible energy storage</subject><subject>Impedance</subject><subject>Nanocomposites</subject><subject>PAN</subject><subject>Polyacrylonitrile</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>Polyvinylidene fluorides</subject><subject>PVDF</subject><subject>Q‐factor</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Zirconium dioxide</subject><issn>1042-7147</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNotkcFu1DAQhiMEEqUg8QgjcU26duw4m-Nqu1sqVdsgFg5cIq89aV05tnG8hbwZj0dCOf2jmW_mH-nPso-UXFFCylWQ6UpUTfMqu6CkaQparenrpeZlUVNev83ejeMTIfOsqS-yPzv3KJ1CDdcGLaoUjcrh-IhxkDaHncP4MMHX5KN8wBy-nKU1aYK9VHMrh9shoF72c5BOw9Y7fVbJPC9MG33AmAyO4Hs4-Ge00H6_3q_azWH1I96X0Ho7DRjhIJ1Xfgh-NGmmex9hb_G3OVmE3b-nvDNqhE0I1iiZjHfj--xNL-2IH_7rZfZtvztuPxd39ze3281dEWhFm6Jkpah50zN1IlwQFHLNtF4TrrmsNO1R9EpQollN2Al5RRiWouJrUSqOPavYZfbp5W6I_ucZx9Q9-XN0s2XHaEkrIijnM1W8UL-MxakL0QwyTh0l3RJKN4fSLaF07ea4KPsLvMqCxw</recordid><startdate>202410</startdate><enddate>202410</enddate><creator>Vilvanatha Prabu, A.</creator><creator>Vijayaraghavan, G. 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V.</creatorcontrib><creatorcontrib>Basheer Ahamed, M.</creatorcontrib><creatorcontrib>Suganya, R.</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vilvanatha Prabu, A.</au><au>Vijayaraghavan, G. 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In this study, novel polymer nanocomposite films based on polyvinylidene fluoride/polyacrylonitrile/zirconium dioxide (PVDF/PAN/ZrO2) were prepared using a solution casting technique. The structural modifications and morphological properties were analyzed by x‐ray diffraction (XRD) and high resolution scanning electron microscopy (HRSEM). The obtained results verified the filler‐polymer interactions and uniform dispersion of the ZrO2 filler in the host polymers (PVDF and PAN). Thermal stability of up to 46% leftover residue for 30% ZrO2 nano‐filler loading in the blend polymer nanocomposite was analyzed by thermogravimetric analysis (TGA). The dielectric properties such as dielectric constant and dielectric loss values and impedance, Q‐factor, and AC conductivity were analyzed using an impedance analyzer. The decrement in impedance with increasing nano‐filler content with improved dielectric, thermal, Q‐factor, energy density and conductivity properties signifies the prepared novel PVDF/PAN/ZrO2 polymer nanocomposite as an effective material for flexible electronics applications.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pat.6599</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0460-7064</orcidid></addata></record> |
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| language | eng |
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| source | Wiley |
| subjects | Dielectric loss Dielectric properties Electronics Fillers Flexible components flexible energy storage Impedance Nanocomposites PAN Polyacrylonitrile Polymer films Polymers Polyvinylidene fluorides PVDF Q‐factor Thermal stability Thermogravimetric analysis Zirconium dioxide |
| title | Enhanced Dielectric, Thermal, Energy Storage, Quality Factor, Impedance, and Conductivity Properties of Novel PVDF/PAN/ZrO2 Polymer Nanocomposites for Flexible Electronics Applications |
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