The impact of aluminum oxide deposition on the high-temperature resistance of silica aerogels

• Published in: Journal of sol-gel science and technology 2024-11, Vol.112 (2), p.624-637
• Main Authors: Gao, Shuai, Han, Meixu, Pan, Jinwen, Zhong, Yang, Jiang, Hongyi
• Format: Article
• Language: English
• Subjects: Aluminum; Aluminum chloride; Aluminum oxide; Ceramics; Chemistry and Materials Science; Composites; Deposition; Glass; High temperature; Impact resistance; Inorganic Chemistry; Materials Science; Nanotechnology; Natural Materials; Optical and Electronic Materials; Original Paper; Pressure; Production costs; Roasting; Room temperature; Silica aerogels; Silicon dioxide; Sol-gel processes; Specific surface; Structural stability; Surface area; Temperature; Thermal resistance; Thermal stability
• ISSN: 0928-0707; 1573-4846
• DOI: 10.1007/s10971-024-06547-x

Silica aerogel (SA) was synthesized through the sol-gel process followed by ambient pressure drying, with aluminum-deposited silica aerogel (ASA) subsequently produced via aluminum deposition using an AlCl 3 ·6H 2 O hydrolysis solution. This study examined the impact of deposition time and calcination temperature on ASA’s characteristics. Compared to the non-aluminum-deposited SA, ASA with 12 h of deposition time (ASA-12h) showcased a significant increase in specific surface area, reaching 675m 2  ∙ g −1 at room temperature. Post-calcination at 800 °C and 1000 °C resulted in specific surface areas of 613m 2  ∙ g −1 and 265m 2  ∙ g −1 , respectively, markedly surpassing those of SA (240 m 2 ∙g −1 at 800 °C and 16m 2  ∙ g −1 at 1000 °C). The results demonstrate that during the aging process, the deposited aluminum is coated by the aging solution, enabling it to remain stable and distribute uniformly. This deposition not only increases the particle size but also enhances structural stability. Furthermore, the formation of new Si-O-Al bonds improves the thermal stability of the silicon dioxide lattices. These insights pave the way for the industrial production of aerogels that are resistant to high temperatures. Graphical Abstract Highlights The production cost was reduced by using acidic silica sol and TEOS as composite silicon sources. The aluminum element is uniformly and stably distributed in the SiO 2 aerogel skeleton by the method of alumina deposition. The high-temperature resistance of aerogel was improved obviously after alumina deposition.