Assembly of Functionalized 3,4‐Fused Tricyclic Benzosultams via Radical‐Promoted Cascade Reactions

A tandem oxidative radical functionalization/annulation of N‐acryloyl amino saccharin is disclosed. This strategy allows the facile construction of diversely functionalized 3,4‐fused tricyclic benzosultams that previously have not been reported. A wide range of functionalities were installed through...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2024-09, Vol.366 (17), p.3624-3630
Main Authors: Reddy, Chada Raji, Kumari, Ankita, Sagar, Banoth Karuna, Patil, Amol D.
Format: Article
Language:English
Subjects:
Acrylamide
Annulation
Benzosultam
Cascade chemical reactions
Cascade Reaction
Chemical reactions
Saccharin
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Summary:A tandem oxidative radical functionalization/annulation of N‐acryloyl amino saccharin is disclosed. This strategy allows the facile construction of diversely functionalized 3,4‐fused tricyclic benzosultams that previously have not been reported. A wide range of functionalities were installed through the formation of C−C, C−S and C−P bond enabled by the respective radicals.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202400419