Iodination of Phenylacetylene and Some Transformations of the Resulting Iodo Derivatives

An efficient procedure has been proposed for the reaction of molecular iodine with phenylacetylene in the presence of cadmium(II) acetate in DMSO at room temperature, and the reactant ratio has been optimized for the iodination process. Mercuration–demercuration of iodoethynylbenzene with molecular...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2024-09, Vol.60 (9), p.1698-1704
Main Authors: Hobosyan, N. G., Balyan, K. V., Pogosyan, H. R., Movsisyan, L. A., Hovsepyan, V. S., Sargsyan, H. B.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Iodination
Iodine
Organic Chemistry
Room temperature
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Summary:An efficient procedure has been proposed for the reaction of molecular iodine with phenylacetylene in the presence of cadmium(II) acetate in DMSO at room temperature, and the reactant ratio has been optimized for the iodination process. Mercuration–demercuration of iodoethynylbenzene with molecular iodine and oxidative homocoupling in the presence of dilithium tetrachlorocuprate have been performed.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428024090124