Loading…
A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries
We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride- co -hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10 −4 S cm −1 ) and Li + transference number (0.74), endowing solid LiFePO 4 //Li batteries with...
Saved in:
| Published in: | Chemical communications (Cambridge, England) England), 2024-11, Vol.6 (92), p.1353-13533 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | cdi_FETCH-LOGICAL-c226t-831a3ab9e0ddb154015dbd12bf8e4ae06e891e7e211e4bb312b33e3df56efc2c3 |
| container_end_page | 13533 |
| container_issue | 92 |
| container_start_page | 1353 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 6 |
| creator | Gong, Xiaoqi Pan, Yaozheng Zhong, Linfeng Wang, Jiasheng Liu, Fujie Qi, Guangsheng Li, Jing Liu, Cong Yu, Dingshan |
| description | We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride-
co
-hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability over 1000 cycles at 60 °C. Our strategy surmounts the ionic conduction-interface stability trade-off and thin dimension-flexibility conflict.
We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability. |
| doi_str_mv | 10.1039/d4cc04550e |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3128242523</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3121591179</sourcerecordid><originalsourceid>FETCH-LOGICAL-c226t-831a3ab9e0ddb154015dbd12bf8e4ae06e891e7e211e4bb312b33e3df56efc2c3</originalsourceid><addsrcrecordid>eNpd0UlLxDAUB_AgijMuF-9KwYsI1aRJOu1xqOMCA14UvJUsr5ihbcYkFebbm1kcwVyS8H55PP5B6ILgO4Jpea-ZUphxjuEAjQnNWcpZ8XG4PvMynVDGR-jE-wWOi_DiGI1oySaY5vkYyWkSwPXCrRJlu6X1JkDSi942RoJLNTjzDToJn6ZPOuikEz0k0IIKzraraBvrEm9bo1MfRLzPTXRBtIkUIXY24M_QUSNaD-e7_RS9P87equd0_vr0Uk3nqcqyPKQFJYIKWQLWWhLO4qhaapLJpgAmAOdQlAQmkBECTEoaK5QC1Q3PoVGZoqfoZtt36ezXAD7UnfEK2jaObAdfxxeEl4RMykiv_9GFHWIK7UYVGct4RqO63SrlrPcOmnrpTBejqgmu18nXD6yqNsnPIr7atRxkB3pPf6OO4HILnFf76t_X0R8FtokC</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3128242523</pqid></control><display><type>article</type><title>A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries</title><source>Royal Society of Chemistry</source><creator>Gong, Xiaoqi ; Pan, Yaozheng ; Zhong, Linfeng ; Wang, Jiasheng ; Liu, Fujie ; Qi, Guangsheng ; Li, Jing ; Liu, Cong ; Yu, Dingshan</creator><creatorcontrib>Gong, Xiaoqi ; Pan, Yaozheng ; Zhong, Linfeng ; Wang, Jiasheng ; Liu, Fujie ; Qi, Guangsheng ; Li, Jing ; Liu, Cong ; Yu, Dingshan</creatorcontrib><description>We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride-
co
-hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability over 1000 cycles at 60 °C. Our strategy surmounts the ionic conduction-interface stability trade-off and thin dimension-flexibility conflict.
We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability.</description><identifier>ISSN: 1359-7345</identifier><identifier>ISSN: 1364-548X</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc04550e</identifier><identifier>PMID: 39470366</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Electrolytes ; Ethylene oxide ; Interface stability ; Ion currents ; Lithium batteries ; Membranes ; Molten salt electrolytes ; Nanofibers ; Polyethylene oxide ; Solid electrolytes ; Vinylidene ; Vinylidene fluoride</subject><ispartof>Chemical communications (Cambridge, England), 2024-11, Vol.6 (92), p.1353-13533</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c226t-831a3ab9e0ddb154015dbd12bf8e4ae06e891e7e211e4bb312b33e3df56efc2c3</cites><orcidid>0000-0002-2913-2432</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39470366$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gong, Xiaoqi</creatorcontrib><creatorcontrib>Pan, Yaozheng</creatorcontrib><creatorcontrib>Zhong, Linfeng</creatorcontrib><creatorcontrib>Wang, Jiasheng</creatorcontrib><creatorcontrib>Liu, Fujie</creatorcontrib><creatorcontrib>Qi, Guangsheng</creatorcontrib><creatorcontrib>Li, Jing</creatorcontrib><creatorcontrib>Liu, Cong</creatorcontrib><creatorcontrib>Yu, Dingshan</creatorcontrib><title>A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride-
co
-hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability over 1000 cycles at 60 °C. Our strategy surmounts the ionic conduction-interface stability trade-off and thin dimension-flexibility conflict.
We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability.</description><subject>Electrolytes</subject><subject>Ethylene oxide</subject><subject>Interface stability</subject><subject>Ion currents</subject><subject>Lithium batteries</subject><subject>Membranes</subject><subject>Molten salt electrolytes</subject><subject>Nanofibers</subject><subject>Polyethylene oxide</subject><subject>Solid electrolytes</subject><subject>Vinylidene</subject><subject>Vinylidene fluoride</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0UlLxDAUB_AgijMuF-9KwYsI1aRJOu1xqOMCA14UvJUsr5ihbcYkFebbm1kcwVyS8H55PP5B6ILgO4Jpea-ZUphxjuEAjQnNWcpZ8XG4PvMynVDGR-jE-wWOi_DiGI1oySaY5vkYyWkSwPXCrRJlu6X1JkDSi942RoJLNTjzDToJn6ZPOuikEz0k0IIKzraraBvrEm9bo1MfRLzPTXRBtIkUIXY24M_QUSNaD-e7_RS9P87equd0_vr0Uk3nqcqyPKQFJYIKWQLWWhLO4qhaapLJpgAmAOdQlAQmkBECTEoaK5QC1Q3PoVGZoqfoZtt36ezXAD7UnfEK2jaObAdfxxeEl4RMykiv_9GFHWIK7UYVGct4RqO63SrlrPcOmnrpTBejqgmu18nXD6yqNsnPIr7atRxkB3pPf6OO4HILnFf76t_X0R8FtokC</recordid><startdate>20241114</startdate><enddate>20241114</enddate><creator>Gong, Xiaoqi</creator><creator>Pan, Yaozheng</creator><creator>Zhong, Linfeng</creator><creator>Wang, Jiasheng</creator><creator>Liu, Fujie</creator><creator>Qi, Guangsheng</creator><creator>Li, Jing</creator><creator>Liu, Cong</creator><creator>Yu, Dingshan</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2913-2432</orcidid></search><sort><creationdate>20241114</creationdate><title>A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries</title><author>Gong, Xiaoqi ; Pan, Yaozheng ; Zhong, Linfeng ; Wang, Jiasheng ; Liu, Fujie ; Qi, Guangsheng ; Li, Jing ; Liu, Cong ; Yu, Dingshan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-831a3ab9e0ddb154015dbd12bf8e4ae06e891e7e211e4bb312b33e3df56efc2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Electrolytes</topic><topic>Ethylene oxide</topic><topic>Interface stability</topic><topic>Ion currents</topic><topic>Lithium batteries</topic><topic>Membranes</topic><topic>Molten salt electrolytes</topic><topic>Nanofibers</topic><topic>Polyethylene oxide</topic><topic>Solid electrolytes</topic><topic>Vinylidene</topic><topic>Vinylidene fluoride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gong, Xiaoqi</creatorcontrib><creatorcontrib>Pan, Yaozheng</creatorcontrib><creatorcontrib>Zhong, Linfeng</creatorcontrib><creatorcontrib>Wang, Jiasheng</creatorcontrib><creatorcontrib>Liu, Fujie</creatorcontrib><creatorcontrib>Qi, Guangsheng</creatorcontrib><creatorcontrib>Li, Jing</creatorcontrib><creatorcontrib>Liu, Cong</creatorcontrib><creatorcontrib>Yu, Dingshan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gong, Xiaoqi</au><au>Pan, Yaozheng</au><au>Zhong, Linfeng</au><au>Wang, Jiasheng</au><au>Liu, Fujie</au><au>Qi, Guangsheng</au><au>Li, Jing</au><au>Liu, Cong</au><au>Yu, Dingshan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2024-11-14</date><risdate>2024</risdate><volume>6</volume><issue>92</issue><spage>1353</spage><epage>13533</epage><pages>1353-13533</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>We develop novel membrane electrolytes comprising h-BN-doped poly(ethylene oxide) modified poly(vinylidene fluoride-
co
-hexafluoropropylene)-nanofibers (h-BN@PEO/PVH) with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability over 1000 cycles at 60 °C. Our strategy surmounts the ionic conduction-interface stability trade-off and thin dimension-flexibility conflict.
We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10
−4
S cm
−1
) and Li
+
transference number (0.74), endowing solid LiFePO
4
//Li batteries with excellent cyclability.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39470366</pmid><doi>10.1039/d4cc04550e</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-2913-2432</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-11, Vol.6 (92), p.1353-13533 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_3128242523 |
| source | Royal Society of Chemistry |
| subjects | Electrolytes Ethylene oxide Interface stability Ion currents Lithium batteries Membranes Molten salt electrolytes Nanofibers Polyethylene oxide Solid electrolytes Vinylidene Vinylidene fluoride |
| title | A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T20%3A56%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20ternary%20composite%20nanofiber-derived%20thin%20membrane%20electrolyte%20for%20solid-state%20Li%20metal%20batteries&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Gong,%20Xiaoqi&rft.date=2024-11-14&rft.volume=6&rft.issue=92&rft.spage=1353&rft.epage=13533&rft.pages=1353-13533&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d4cc04550e&rft_dat=%3Cproquest_cross%3E3121591179%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c226t-831a3ab9e0ddb154015dbd12bf8e4ae06e891e7e211e4bb312b33e3df56efc2c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3128242523&rft_id=info:pmid/39470366&rfr_iscdi=true |