Synthesis and structure of chlororuthenacyclopentatriene

The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computatio...

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Bibliographic Details
Published in:Inorganic chemistry frontiers 2024-11, Vol.11 (23), p.8479-8488
Main Authors: Chu, Zhenwei, Peng, Zhishun, Xu, Cheng, Hua, Yuhui, He, Guomei, Chen, Jiangxi, Jia, Guochen
Format: Article
Language:English
Subjects:
Chemical synthesis
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Summary:The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computational studies provided evidence for their aromatic character, making them an important supplement to the rare aromatic ruthenacycle family.
ISSN:2052-1545
2052-1553
DOI:10.1039/d4qi01833h