Synthesis and structure of chlororuthenacyclopentatriene

The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computatio...

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Published in:Inorganic chemistry frontiers 2024-11, Vol.11 (23), p.8479-8488
Main Authors: Chu, Zhenwei, Peng, Zhishun, Xu, Cheng, Hua, Yuhui, He, Guomei, Chen, Jiangxi, Jia, Guochen
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container_title Inorganic chemistry frontiers
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creator Chu, Zhenwei
Peng, Zhishun
Xu, Cheng
Hua, Yuhui
He, Guomei
Chen, Jiangxi
Jia, Guochen
description The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computational studies provided evidence for their aromatic character, making them an important supplement to the rare aromatic ruthenacycle family.
doi_str_mv 10.1039/d4qi01833h
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title Synthesis and structure of chlororuthenacyclopentatriene
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