Preparation and Characterization of a Novel Ca-Fe-Si-S Composite for the Simultaneous Stabilization of Heavy Metals in Arsenic Slag

• Published in: Water, air, and soil pollution air, and soil pollution, 2024-12, Vol.235 (12), p.822, Article 822
• Main Authors: Zhang, Ge, Yang, Huifen, Lin, Xingjie, Miao, Yu, Zhang, Chi, Li, Fangze, Pang, Zhikun, Xin, Xin
• Format: Article
• Language: English
• Subjects: Anion exchange; Anion exchanging; Anions; Arsenic; Atmospheric Protection/Air Quality Control/Air Pollution; Cadmium; Calcium; Calcium carbonate; Calcium carbonates; Calcium ferrous silicates; Calcium hydroxide; Calcium sulfate; Carbonates; Chemical precipitation; Chemical reactions; Climate Change/Climate Change Impacts; Composite materials; Copper; Decomposition; Decomposition reactions; Dehydration; Dicalcium silicate; Earth and Environmental Science; Environment; Ferrous silicates; Geographical distribution; Gypsum; Heavy metals; High temperature; Hydrogeology; Hydroxides; Iron; Iron sulfides; Leaching; Metals; Multifunctional materials; Pyrolysis; Silicates; Silicon; Slag; Slaked lime; Soil Science & Conservation; Stabilization; Stabilizing; Water Quality/Water Pollution; Zinc
• ISSN: 0049-6979; 1573-2932
• DOI: 10.1007/s11270-024-07616-1

In this work, a novel Ca-Fe-Si-S composite was prepared from thermal desorption residue through FeSO 4 impregnation-pyrolysis. The characteristics and modification process of the composite were specified through a series of analytical methods. And stabilization experiments were conducted to investigate the performance of prepared materials. The optimal Ca–Fe–Si–S composite was obtained at impregnation ratio of 10%, pyrolysis temperature of 900℃ and pyrolysis time of 60 min. The modification process included the dissolution of calcium hydroxide, the formation of gypsum and ferrous silicate, the dehydration of gypsum, the reduction decomposition of calcium sulfate, the decomposition of calcium carbonate and the solid reaction at high temperature. The obtained optimal Ca–Fe–Si–S composite was a multifunctional material mainly composed of high contents of Ca, Fe, Si, S, which corresponding to FeS, CaS, Ca 2 SiO 4 , Ca 3 Al 2 (SiO 4 ) 3 , Ca 3 Fe 2 (SiO 4 ) 3 , Ca 5 (SiO 4 ) 2 SO 4 . The application of 5% optimal Ca–Fe–Si–S composite successfully lowed the leaching concentrations of As, Zn, Cu, Cd in arsenic slag to meet the discharging standard. Meanwhile, the non-specifically bound and specifically bound of As totally decreased by 3.72%, and the acid extractable species of Zn, Cu, Cd reduced by 11.20%, 29.37%, 2.76% respectively. The distribution of stable species for heavy metals significantly increased as united results of surface complexation, chemical precipitation and ion/anion exchange reactions between the prepared composite and heavy metals. The findings of this research provide an effective material for the simultaneous stabilization of multiple heavy metals.