Effect of synergistic action of anodising and graphene on the mechanical properties of fibre-reinforced metal laminates

• Published in: Journal of adhesion science and technology 2024-11, Vol.38 (22), p.4137-4158
• Main Authors: Zhao, Changlin, Dai, Xinming, Liu, Xinying, Cui, Xu
• Format: Article
• Language: English
• Subjects: Aluminum base alloys; Anodising; Anodizing; Fiber reinforced metals; Fiber reinforced polymers; Flexural strength; FMLs; Fracture toughness; Glass fiber reinforced plastics; Glass-epoxy composites; Graphene; Graphene nanoplatelets; Image enhancement; Interlayers; Laminates; Mechanical properties; Oxidation; Resins; Shear strength; Synergistic effect; Tensile strength
• ISSN: 0169-4243; 1568-5616
• DOI: 10.1080/01694243.2024.2365418

Fibre reinforced metal laminates (FMLs) are widely used in various fields due to their excellent properties. However, the weak interlayer properties of FMLs limit their applications. In this paper, the interlayer properties of FMLs are enhanced by anodising the 2024-T3 aluminium alloy layer in FMLs or by epoxy matrix modification of graphene nanoplatelets (GNPs). The effect of both synergistic impacts on the interlayer properties of most FMLs is investigated. The FMLs were manufactured using the wet lay-up technique using 2024-T3 aluminium alloy, E51 epoxy and EW100 glass fibre. The results showed that the type I fracture toughness, tensile strength, flexural strength, interlayer shear strength and single layer shear strength of FMLs after anodic oxidation treatment were increased by 406.4%, 10.3%, 18.3%, 42.6% and 28.3%, respectively, compared with those of pure FMLs. The type I fracture toughness, tensile strength, flexural strength, interlayer shear strength and single layer shear strength of the GNPs-modified FMLs matrix were increased by 280.4%, 3.7%, 6.8%, 34.5% and 19.1%, respectively, compared with those of pure FMLs. Moreover, the synergistic effect of FMLs indicates that the simultaneous anodic oxidation and GNPs modification of FMLs can lead to the best mechanical properties of FMLs. Microscopic images and schematics illustrate the toughening mechanism of anodising and GNPs, including the enhancement of aluminium/resin interface and fibre/resin interface and the enhancement of resin matrix properties.