Recent Advances in Methodologies for Radical‐Mechanistic Borylation

Comprehensive Summary We reviewed works on radical borylation reactions since 2020 from two aspects. 1. Borylation from alkyl or aryl radicals: This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids, followed by their reaction wit...

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Bibliographic Details
Published in:Chinese journal of chemistry 2025-01, Vol.43 (1), p.104-115
Main Authors: Lian, Chang, Zhang, Jianning, Qiu, Di, Mo, Fanyang
Format: Article
Language:English
Subjects:
Aromatic compounds
Boranes
Boron
Carboxylic acids
Esters
Green chemistry
Halides
Organic methodologies
Radical mechanisms
Radical reactions
Radicals
Reagents
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Summary:Comprehensive Summary We reviewed works on radical borylation reactions since 2020 from two aspects. 1. Borylation from alkyl or aryl radicals: This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids, followed by their reaction with diboron reagents to form boron esters. 2. Borylation from boron‐centered radicals: This approach involves generating boron‐centered radicals, which then react with substrates to achieve borylation. Key Scientists In this article, we review the research on radical borylation reactions since 2020. Two aspects are focused on respectively: the borylation of alkyl or aryl radicals, and the boron‐centered radical reaction. We believe that the development of radical borylation strategies has great potential in the future.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.202400694