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Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass
Calcium aluminosilicate (CaO-Al 2 O 3 -SiO 2 , CAS) glass, with varying B 2 O 3 to Al 2 O 3 substitutions, was prepared using the melting method. The network structure of this CAS glass was analyzed through Raman spectroscopy and nuclear magnetic resonance spectroscopy. The results showed as the B 2...
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| Published in: | Journal of materials science. Materials in electronics 2024-12, Vol.35 (35), p.2220, Article 2220 |
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| container_title | Journal of materials science. Materials in electronics |
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| creator | Qin, Xinjie Wei, Zecong Fan, Zhenhua Xiong, Dehua Wang, Yingxin Teng, Zhou Zhang, Jihong Xie, Jun |
| description | Calcium aluminosilicate (CaO-Al
2
O
3
-SiO
2
, CAS) glass, with varying B
2
O
3
to Al
2
O
3
substitutions, was prepared using the melting method. The network structure of this CAS glass was analyzed through Raman spectroscopy and nuclear magnetic resonance spectroscopy. The results showed as the B
2
O
3
to Al
2
O
3
substitution increased, the proportion of [BO
4
] gradually decreased from 57.2 to 41.6%, while the proportion of [BO
3
] increased from 42.8 to 58.4%. The primary form of Al
3+
mainly exists in the glass network structure is [AlO
4
]. The Q
n
group is dominated by Q
2
(25.6 ~ 35.0%) units and Q
3
(51.8 ~ 65.5%) units. As the B
2
O
3
substitution for Al
2
O
3
increased, there was a gradual decrease in Q
1
and Q
2
units, and a corresponding increase in Q
3
units and Q
4
units, leading to an increase in the degree of polymerization of glass network structure. However, the substitution also reduced the stability of the glass network structure. While the replacement of Al
2
O
3
by B
2
O
3
diminished the hardness, bending strength, expansion softening temperature and other properties of the glass, it significantly reduced the viscous activation energy, melting temperature, and forming temperature of the glass. These changes have significant implications for practical industrial production. |
| doi_str_mv | 10.1007/s10854-024-13982-7 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3141685988</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3141685988</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-2463eb8275cb3d1329e9e22674f85ccba8bd89fd3b898d9f4780a60e2ba5b8ff3</originalsourceid><addsrcrecordid>eNp9kEtLAzEQx4MoWB9fwFPAczSv3STHWuoDCr0oeAtJNqkp292ax8Fv79YK3jwNM_x_M8MPgBuC7wjG4j4TLBuOMOWIMCUpEidgRhrBEJf0_RTMsGoE4g2l5-Ai5y3GuOVMzkBYhuBdgWOAD3TNYK42l1hqieMAw5jgvD-Mp6Z8eJhLqq7U5KEZOrhP496nEn0-4M70LtYdNH3dxWHMsY_OFA83vcn5CpwF02d__Vsvwdvj8nXxjFbrp5fFfIUcxbggylvmraSicZZ1hFHllae0FTzIxjlrpO2kCh2zUslOBS4kNi321JrGyhDYJbg97p1--6w-F70daxqmk5oRTlrZKCmnFD2mXBpzTj7ofYo7k740wfrgUx996smn_vGpxQSxI5Sn8LDx6W_1P9Q3gaF5Jg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3141685988</pqid></control><display><type>article</type><title>Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass</title><source>Springer Nature</source><creator>Qin, Xinjie ; Wei, Zecong ; Fan, Zhenhua ; Xiong, Dehua ; Wang, Yingxin ; Teng, Zhou ; Zhang, Jihong ; Xie, Jun</creator><creatorcontrib>Qin, Xinjie ; Wei, Zecong ; Fan, Zhenhua ; Xiong, Dehua ; Wang, Yingxin ; Teng, Zhou ; Zhang, Jihong ; Xie, Jun</creatorcontrib><description>Calcium aluminosilicate (CaO-Al
2
O
3
-SiO
2
, CAS) glass, with varying B
2
O
3
to Al
2
O
3
substitutions, was prepared using the melting method. The network structure of this CAS glass was analyzed through Raman spectroscopy and nuclear magnetic resonance spectroscopy. The results showed as the B
2
O
3
to Al
2
O
3
substitution increased, the proportion of [BO
4
] gradually decreased from 57.2 to 41.6%, while the proportion of [BO
3
] increased from 42.8 to 58.4%. The primary form of Al
3+
mainly exists in the glass network structure is [AlO
4
]. The Q
n
group is dominated by Q
2
(25.6 ~ 35.0%) units and Q
3
(51.8 ~ 65.5%) units. As the B
2
O
3
substitution for Al
2
O
3
increased, there was a gradual decrease in Q
1
and Q
2
units, and a corresponding increase in Q
3
units and Q
4
units, leading to an increase in the degree of polymerization of glass network structure. However, the substitution also reduced the stability of the glass network structure. While the replacement of Al
2
O
3
by B
2
O
3
diminished the hardness, bending strength, expansion softening temperature and other properties of the glass, it significantly reduced the viscous activation energy, melting temperature, and forming temperature of the glass. These changes have significant implications for practical industrial production.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-024-13982-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminosilicates ; Aluminum oxide ; Aluminum silicates ; Bend strength ; Boron oxides ; Calcium ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Degree of polymerization ; Materials Science ; Melt temperature ; NMR spectroscopy ; Optical and Electronic Materials ; Raman spectroscopy ; Silicon dioxide ; Spectrum analysis ; Substitutes</subject><ispartof>Journal of materials science. Materials in electronics, 2024-12, Vol.35 (35), p.2220, Article 2220</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. Dec 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-2463eb8275cb3d1329e9e22674f85ccba8bd89fd3b898d9f4780a60e2ba5b8ff3</cites><orcidid>0000-0002-4714-9019</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Qin, Xinjie</creatorcontrib><creatorcontrib>Wei, Zecong</creatorcontrib><creatorcontrib>Fan, Zhenhua</creatorcontrib><creatorcontrib>Xiong, Dehua</creatorcontrib><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Teng, Zhou</creatorcontrib><creatorcontrib>Zhang, Jihong</creatorcontrib><creatorcontrib>Xie, Jun</creatorcontrib><title>Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Calcium aluminosilicate (CaO-Al
2
O
3
-SiO
2
, CAS) glass, with varying B
2
O
3
to Al
2
O
3
substitutions, was prepared using the melting method. The network structure of this CAS glass was analyzed through Raman spectroscopy and nuclear magnetic resonance spectroscopy. The results showed as the B
2
O
3
to Al
2
O
3
substitution increased, the proportion of [BO
4
] gradually decreased from 57.2 to 41.6%, while the proportion of [BO
3
] increased from 42.8 to 58.4%. The primary form of Al
3+
mainly exists in the glass network structure is [AlO
4
]. The Q
n
group is dominated by Q
2
(25.6 ~ 35.0%) units and Q
3
(51.8 ~ 65.5%) units. As the B
2
O
3
substitution for Al
2
O
3
increased, there was a gradual decrease in Q
1
and Q
2
units, and a corresponding increase in Q
3
units and Q
4
units, leading to an increase in the degree of polymerization of glass network structure. However, the substitution also reduced the stability of the glass network structure. While the replacement of Al
2
O
3
by B
2
O
3
diminished the hardness, bending strength, expansion softening temperature and other properties of the glass, it significantly reduced the viscous activation energy, melting temperature, and forming temperature of the glass. These changes have significant implications for practical industrial production.</description><subject>Aluminosilicates</subject><subject>Aluminum oxide</subject><subject>Aluminum silicates</subject><subject>Bend strength</subject><subject>Boron oxides</subject><subject>Calcium</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Degree of polymerization</subject><subject>Materials Science</subject><subject>Melt temperature</subject><subject>NMR spectroscopy</subject><subject>Optical and Electronic Materials</subject><subject>Raman spectroscopy</subject><subject>Silicon dioxide</subject><subject>Spectrum analysis</subject><subject>Substitutes</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEQx4MoWB9fwFPAczSv3STHWuoDCr0oeAtJNqkp292ax8Fv79YK3jwNM_x_M8MPgBuC7wjG4j4TLBuOMOWIMCUpEidgRhrBEJf0_RTMsGoE4g2l5-Ai5y3GuOVMzkBYhuBdgWOAD3TNYK42l1hqieMAw5jgvD-Mp6Z8eJhLqq7U5KEZOrhP496nEn0-4M70LtYdNH3dxWHMsY_OFA83vcn5CpwF02d__Vsvwdvj8nXxjFbrp5fFfIUcxbggylvmraSicZZ1hFHllae0FTzIxjlrpO2kCh2zUslOBS4kNi321JrGyhDYJbg97p1--6w-F70daxqmk5oRTlrZKCmnFD2mXBpzTj7ofYo7k740wfrgUx996smn_vGpxQSxI5Sn8LDx6W_1P9Q3gaF5Jg</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Qin, Xinjie</creator><creator>Wei, Zecong</creator><creator>Fan, Zhenhua</creator><creator>Xiong, Dehua</creator><creator>Wang, Yingxin</creator><creator>Teng, Zhou</creator><creator>Zhang, Jihong</creator><creator>Xie, Jun</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-4714-9019</orcidid></search><sort><creationdate>20241201</creationdate><title>Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass</title><author>Qin, Xinjie ; Wei, Zecong ; Fan, Zhenhua ; Xiong, Dehua ; Wang, Yingxin ; Teng, Zhou ; Zhang, Jihong ; Xie, Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-2463eb8275cb3d1329e9e22674f85ccba8bd89fd3b898d9f4780a60e2ba5b8ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aluminosilicates</topic><topic>Aluminum oxide</topic><topic>Aluminum silicates</topic><topic>Bend strength</topic><topic>Boron oxides</topic><topic>Calcium</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Degree of polymerization</topic><topic>Materials Science</topic><topic>Melt temperature</topic><topic>NMR spectroscopy</topic><topic>Optical and Electronic Materials</topic><topic>Raman spectroscopy</topic><topic>Silicon dioxide</topic><topic>Spectrum analysis</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qin, Xinjie</creatorcontrib><creatorcontrib>Wei, Zecong</creatorcontrib><creatorcontrib>Fan, Zhenhua</creatorcontrib><creatorcontrib>Xiong, Dehua</creatorcontrib><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Teng, Zhou</creatorcontrib><creatorcontrib>Zhang, Jihong</creatorcontrib><creatorcontrib>Xie, Jun</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qin, Xinjie</au><au>Wei, Zecong</au><au>Fan, Zhenhua</au><au>Xiong, Dehua</au><au>Wang, Yingxin</au><au>Teng, Zhou</au><au>Zhang, Jihong</au><au>Xie, Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2024-12-01</date><risdate>2024</risdate><volume>35</volume><issue>35</issue><spage>2220</spage><pages>2220-</pages><artnum>2220</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Calcium aluminosilicate (CaO-Al
2
O
3
-SiO
2
, CAS) glass, with varying B
2
O
3
to Al
2
O
3
substitutions, was prepared using the melting method. The network structure of this CAS glass was analyzed through Raman spectroscopy and nuclear magnetic resonance spectroscopy. The results showed as the B
2
O
3
to Al
2
O
3
substitution increased, the proportion of [BO
4
] gradually decreased from 57.2 to 41.6%, while the proportion of [BO
3
] increased from 42.8 to 58.4%. The primary form of Al
3+
mainly exists in the glass network structure is [AlO
4
]. The Q
n
group is dominated by Q
2
(25.6 ~ 35.0%) units and Q
3
(51.8 ~ 65.5%) units. As the B
2
O
3
substitution for Al
2
O
3
increased, there was a gradual decrease in Q
1
and Q
2
units, and a corresponding increase in Q
3
units and Q
4
units, leading to an increase in the degree of polymerization of glass network structure. However, the substitution also reduced the stability of the glass network structure. While the replacement of Al
2
O
3
by B
2
O
3
diminished the hardness, bending strength, expansion softening temperature and other properties of the glass, it significantly reduced the viscous activation energy, melting temperature, and forming temperature of the glass. These changes have significant implications for practical industrial production.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-024-13982-7</doi><orcidid>https://orcid.org/0000-0002-4714-9019</orcidid></addata></record> |
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| ispartof | Journal of materials science. Materials in electronics, 2024-12, Vol.35 (35), p.2220, Article 2220 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_3141685988 |
| source | Springer Nature |
| subjects | Aluminosilicates Aluminum oxide Aluminum silicates Bend strength Boron oxides Calcium Characterization and Evaluation of Materials Chemistry and Materials Science Degree of polymerization Materials Science Melt temperature NMR spectroscopy Optical and Electronic Materials Raman spectroscopy Silicon dioxide Spectrum analysis Substitutes |
| title | Effect of B2O3 substitution for Al2O3 on the structure and properties of calcium aluminosilicate glass |
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