1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

The reactions of SbI 3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI 4 ]} ( I ) and (3-Br-1-MePy){[SbI 4 ]} ( II ). Specific features of the crystal structures are determined by X-ray diffraction...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of coordination chemistry 2024, Vol.50 (10), p.809-816
Main Authors: Shentseva, I. A., Usol’tsev, A. N., Korobeinikov, N. A., Adonin, S. A.
Format: Article
Language:English
Subjects:
Acetonitrile
Cationic polymerization
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
Thermal stability
Thermogravimetry
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The reactions of SbI 3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI 4 ]} ( I ) and (3-Br-1-MePy){[SbI 4 ]} ( II ). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328424600700