Monomerization of Binuclear Complex [Zn2(Piv)4(Phen)2] under the Action of Water

The interaction of the binuclear complex [Zn 2 (Рiv) 4 (Рhen) 2 ] with water in toluene or acetonitrile results in its monomerization with the formation of compound [Zn(Рiv) 2 (H 2 O)(Рhen)], the crystal structure of which is determined by XRD (CIF file CСDC no. 2374361). The individual character of...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2024-10, Vol.50 (10), p.866-872
Main Authors: Samulionis, A. S., Medvedev, A. G., Tripol’skaya, T. A., Kiskin, M. A., Prikhodchenko, P. V., Eremenko, I. L., Nikolaevskii, S. A.
Format: Article
Language:English
Subjects:
Acetonitrile
Chemistry
Chemistry and Materials Science
Crystal structure
Inorganic Chemistry
Physical Chemistry
Single crystals
Toluene
X-ray diffraction
Zinc peroxide
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Summary:The interaction of the binuclear complex [Zn 2 (Рiv) 4 (Рhen) 2 ] with water in toluene or acetonitrile results in its monomerization with the formation of compound [Zn(Рiv) 2 (H 2 O)(Рhen)], the crystal structure of which is determined by XRD (CIF file CСDC no. 2374361). The individual character of the formed crystalline phase is confirmed by powder XRD. Nanoparticles of zinc peroxide/hydroxide are proposed to be used as a water source for the obtaining of single crystals of [Zn(Рiv) 2 (H 2 O)(Рhen)] suitable for XRD.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328424601006