Visible Light Photoredox‐Catalyzed Three‐Component Reaction of Styrenes with Malonic Esters and CO2

A visible light photoredox‐catalyzed bifunctionalization of styrenes with malonic esters and CO2 to form two C(sp3)−C bonds has been developed. The reaction proceeds at room temperature with 0.1 mol% of the organic photocatalyst (4DPAIPN) and cesium carbonate as a base at a CO2 pressure of 4 atm. Th...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2025-01, Vol.367 (1), p.n/a
Main Authors: Kharlamova, Alisa D., Averin, Alexei D., Bondarenko, Grigoriy N., Abel, Anton S., Beletskaya, Irina P.
Format: Article
Language:English
Subjects:
Bifunctionalisation
Carbon dioxide
Carbon dioxide fixation
Cesium
Esters
Malonic esters
Photocatalysis
Room temperature
Styrenes
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Summary:A visible light photoredox‐catalyzed bifunctionalization of styrenes with malonic esters and CO2 to form two C(sp3)−C bonds has been developed. The reaction proceeds at room temperature with 0.1 mol% of the organic photocatalyst (4DPAIPN) and cesium carbonate as a base at a CO2 pressure of 4 atm. This results in the production of 3‐arylpropane‐1,1,3‐tricarboxylic acid esters in yields ranging from 48% to 99%.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202400956