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Novel Iodine Reagent System for Regioselective Cleavage of Epoxides to Alcohols

Epoxides are converted regioselectively to corresponding higher substituted alcohols with greater yields using diphosphorus tetraiodide (P 2 I 4 ) as a reducing agent and a catalytic amount of tetraethylammonium bromide at room temperature.

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Published in:Synthetic communications 2010-06, Vol.40 (14), p.2108-2112
Main Authors: Telvekar, Vikas N., Rane, Rajesh A.
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Language:English
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description Epoxides are converted regioselectively to corresponding higher substituted alcohols with greater yields using diphosphorus tetraiodide (P 2 I 4 ) as a reducing agent and a catalytic amount of tetraethylammonium bromide at room temperature.
doi_str_mv 10.1080/00397910903219492
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identifier ISSN: 0039-7911
ispartof Synthetic communications, 2010-06, Vol.40 (14), p.2108-2112
issn 0039-7911
1532-2432
language eng
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source Taylor and Francis Science and Technology Collection
subjects Alcohols
diphosphorus tetraiodide
epoxides
reduction
tetraethylammonium bromide
title Novel Iodine Reagent System for Regioselective Cleavage of Epoxides to Alcohols
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