Microwave-assisted synthesis and characterization of a new metal-free and metallophthalocyanines

Dinitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 4-phenoxyphenol (1) with 4-nitrophthalonitrile (2). The metal-free phthalocyanine (4) was prepared by the reaction of dinitrile monomer (3) with DMAE. Ni(II), Co(II), and Zn(II) metallophthalocyanines were prepared by the...

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Bibliographic Details
Published in:Journal of coordination chemistry 2010-03, Vol.63 (5), p.861-867
Main Authors: Kılıçaslan, Meltem B., Ağın, Fatma, Kantekin, Halit
Format: Article
Language:English
Subjects:
Microwave
Phthalocyanine
Phthalonitrile
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Summary:Dinitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 4-phenoxyphenol (1) with 4-nitrophthalonitrile (2). The metal-free phthalocyanine (4) was prepared by the reaction of dinitrile monomer (3) with DMAE. Ni(II), Co(II), and Zn(II) metallophthalocyanines were prepared by the reaction of 3 with chlorides of Ni(II), Co(II), and Zn(II) in DMAE. The new compounds were characterized by IR, 1 H- and 13 C-NMR, UV-Vis, elemental analysis, and MS specral data.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958971003645953