Polystyrene-Anchored Palladium(II) Schiff Base Complex: A Reusable Catalyst for Phosphine-Free and Copper-Free Sonogashira Cross-Coupling Reaction in Aqueous Medium

A novel polystyrene-supported palladium(II) complex, an excellent and recyclable catalyst, was synthesized for Sonogashira reactions. The present complex shows high catalytic activity for Sonogashira cross-coupling reaction of aryl halides with phenylacetylene under phosphine-free and copper-free re...

Full description

Saved in:
Bibliographic Details
Published in:Synthetic communications 2011-09, Vol.41 (17), p.2583-2593
Main Authors: Islam, Manirul, Mondal, P., Roy, A. Singha, Tuhina, K., Mondal, S., Hossain, D.
Format: Article
Language:English
Subjects:
Aqueous medium
aryl halides
Chemical industry
Chemistry
Copper
palladium(II) complex
Sonogashira cross-coupling
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A novel polystyrene-supported palladium(II) complex, an excellent and recyclable catalyst, was synthesized for Sonogashira reactions. The present complex shows high catalytic activity for Sonogashira cross-coupling reaction of aryl halides with phenylacetylene under phosphine-free and copper-free reaction conditions in aqueous (DMF-H 2 O) medium. The catalyst could be reused for at least six reaction cycles with almost unchanged catalytic properties.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397911.2010.515331