Mössbauer investigations of the metastable Fe23B6 phase

Mössbauer spectroscopy was used to study hyperfine interactions in the metastable phase Fe^sub 23^B^sub 6^ that was for the first time obtained in macroscopic amounts in an almost single-phase state. Parameters of ^sup 57^Fe(300 K) spectra, as well as local and average magnetic moments at iron atoms...

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Published in:Physics of metals and metallography 2006-05, Vol.101 (5), p.456-466
Main Authors: Barinov, V. A., Tsurin, V. A., Voronin, V. I., Novikov, S. I., Surikov, V. T.
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Spectrum analysis
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description Mössbauer spectroscopy was used to study hyperfine interactions in the metastable phase Fe^sub 23^B^sub 6^ that was for the first time obtained in macroscopic amounts in an almost single-phase state. Parameters of ^sup 57^Fe(300 K) spectra, as well as local and average magnetic moments at iron atoms have been calculated. It is indicated that the specific features of Mössbauer spectra and hyperfine-field distributions P(H) in mechanically synthesized Fe^sub 23^B^sub 6^ compounds are determined by the modification of the parameters of local surroundings of Fe atoms in positions 48h and 32f of the unit cell.[PUBLICATION ABSTRACT]
doi_str_mv 10.1134/S0031918X06050073
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title Mössbauer investigations of the metastable Fe23B6 phase
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