Synthesis and reactivity of N,N-bis(diphenylphosphino)dimethylaniline compounds

New chalcogenides and complexes of N,N-bis(diphenylphosphino)dimethylanilines were prepared by the reaction of N,N-bis(diphenylphosphino)dimethylaniline ligands with aqueous H^sub 2^O^sub 2^, elemental S and Se and transition metal complexes based on Cu, Pd and Pt. All the new compounds have been ch...

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Bibliographic Details
Published in:Transition metal chemistry (Weinheim) 2007-10, Vol.32 (7), p.877-883
Main Authors: Biricik, Nermin, Durap, Feyyaz, Gümgüm, Bahattin, Fei, Zhaofu, Scopelliti, Rosario
Format: Article
Language:English
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Summary:New chalcogenides and complexes of N,N-bis(diphenylphosphino)dimethylanilines were prepared by the reaction of N,N-bis(diphenylphosphino)dimethylaniline ligands with aqueous H^sub 2^O^sub 2^, elemental S and Se and transition metal complexes based on Cu, Pd and Pt. All the new compounds have been characterised by spectroscopy and the molecular structures of the three complexes of N,N-bis(diphenylphosphino)dimethylanilines have been determined by X-ray crystallography.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1007/s11243-007-0231-5