Copper(II) complexes of 2-pyridineformamide N(4)-methylthiosemicarbazone

Reduction of 2-cyanopyridine by sodium in dry MeOH in the presence of N(4)-methylthiosemicarbazide produces 2-pyridineformamide N(4)-methylthiosemicarbazone, HAm4M. Copper(II) complexes have been prepared and characterized by molar conductivities, magnetic susceptibilities and spectroscopic techniqu...

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Bibliographic Details
Published in:Transition metal chemistry (Weinheim) 2000-02, Vol.25 (1), p.80
Main Authors: West, Douglas X, Swearingen, John K, El-sawaf, Ayman K
Format: Article
Language:English
Online Access:Get full text
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Summary:Reduction of 2-cyanopyridine by sodium in dry MeOH in the presence of N(4)-methylthiosemicarbazide produces 2-pyridineformamide N(4)-methylthiosemicarbazone, HAm4M. Copper(II) complexes have been prepared and characterized by molar conductivities, magnetic susceptibilities and spectroscopic techniques. Coordination is via the pyridyl nitrogen, imine nitrogen and thione or thiolato sulfur, when coordinating as the neutral or anionic ligand, respectively.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1023/A:1007034627143