Novel vanadyl complexes with 2-hydroxy-3-methyl-2-cyclopenten-1-one

Two examples of novel vanadyl complexes of 2-hydroxy-3-methyl-2-cyclopenten-1-one, Hmcp, with 1:2 stoichiometry have been characterised by elemental analysis, i.r. and optical spectral studies. [VOCl^sub 2^(H^sub 2^O)(Hmcp)^sub 2^] (1) contains neutral Hmcp coordinated to vanadium through a carbonyl...

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Bibliographic Details
Published in:Transition metal chemistry (Weinheim) 2003-08, Vol.28 (5), p.568
Main Authors: Grybo, Ryszard, Samotus, Alina, Asocha, Wiesaw
Format: Article
Language:English
Online Access:Get full text
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Summary:Two examples of novel vanadyl complexes of 2-hydroxy-3-methyl-2-cyclopenten-1-one, Hmcp, with 1:2 stoichiometry have been characterised by elemental analysis, i.r. and optical spectral studies. [VOCl^sub 2^(H^sub 2^O)(Hmcp)^sub 2^] (1) contains neutral Hmcp coordinated to vanadium through a carbonyl oxygen and both molecules are trans to each other. [VO(mcp)^sub 2^H^sub 2^O] (2) contains the mono-anionic form of Hmcp. Both complexes have distorted octahedral geometry.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1023/A:1025029127320