Oxidation of ambient biogenic secondary organic aerosol by hydroxyl radicals: Effects on cloud condensation nuclei activity

• Published in: Geophysical research letters 2011-11, Vol.38 (22), p.n/a
• Main Authors: Wong, J. P. S., Lee, A. K. Y., Slowik, J. G., Cziczo, D. J., Leaitch, W. R., Macdonald, A., Abbatt, J. P. D.
• Format: Article
• Language: English
• Subjects: Aerosols; Atmospheric aerosols; Atmospheric sciences; CCN activity; Chemistry; cloud condensation nuclei; Clouds; Earth sciences; Earth, ocean, space; Evolution; Exact sciences and technology; forested site; Hydroxyl radicals; mass spectrometer; OH oxidation; organic aerosol; Oxidation; Oxygenation; Photooxidation; Physics; Troposphere
• ISSN: 0094-8276; 1944-8007
• DOI: 10.1029/2011GL049351

Changes in the hygroscopicity of ambient biogenic secondary organic aerosols (SOA) due to controlled OH oxidation were investigated at a remote forested site at Whistler Mountain, British Columbia during July of 2010. Coupled photo‐oxidation and cloud condensation nuclei (CCN) experiments were conducted on: i) ambient particles exposed to high levels of gas‐phase OH, and ii) the water‐soluble fraction of ambient particles oxidized by aqueous‐phase OH. An Aerodyne Aerosol Mass Spectrometer (AMS) monitored the changes in the chemical composition and degree of oxidation (O:C ratio) of the organic component of ambient aerosol due to OH oxidation. The CCN activity of size‐selected particles was measured to determine the hygroscopicity parameter (κorg,CCN) for particles of various degrees of oxygenation. In both cases, the CCN activity of the oxidized material was higher than that of the ambient particles. In general, κorg,CCN of the aerosol increases with its O:C ratio, in agreement with previous laboratory measurements. Key Points OH oxidation leads to an increase in ambient organic aerosol hygroscopicity Both gas‐ and aqueous‐OH oxidation are important aerosol aging processes Trend of CCN activity with SOA oxidation state agrees with previous lab studies