Chemically modified silica gel for selective solid-phase extraction and preconcentration of heavy metal ions

• Published in: International journal of environmental analytical chemistry 2011-12, Vol.91 (15), p.1466-1476
• Main Authors: Rykowska, Iwona, Wasiak, Wiesław
• Format: Article
• Language: English
• Subjects: Chemical synthesis; chemically modified silica gel; Chromium; Copper; Extraction; Extraction processes; heavy metal ions; Lakes; Metal ions; NMR; Nuclear magnetic resonance; solid-phase extraction; Sorbents; Trace elements; Zinc
• ISSN: 0306-7319; 1029-0397
• DOI: 10.1080/03067319.2010.525745

This paper describes our research on the synthesis of the sorbent with chemically bonded ketoimine groups, and, furthermore, using this sorbent in the SPE technique to extract and preconcentrate trace amounts of metal ions in water samples. Surface characteristics of the sorbent were determined by elemental analysis, NMR spectra for the solid phases ( 29 Si CP MAS NMR), and analysis of pore size distribution of the sorbent and nitrogen adsorption-desorption. The newly proposed sorbent with ketoimine groups was applied for the extraction and preconcentration of trace amounts of Cu (II), Cr (III) and Zn (II) ions from the water from a lake, post-industrial water and purified water unburdened back to the lake. The determination of the transition-metal ions was performed on an emission spectroscope with inductively coupled plasma ICP-OES. For the batch method, the optimum pH range for Cu (II) and Cr (III) extraction was equal to 5, and Zn(II)-to 8. All the metal ions can be desorbed from SPE columns with 10 mL of 0.5 mol HNO 3 . The detection limits of the method were found to be 0.7 µg L −1 for Cu (II), 0.08 µg L −1 for Cr (III), and 0.2 µg L −1 for Zn (II), respectively.