Effects of Specific Adsorption on the Differential Capacitance of Imidazolium-Based Ionic Liquid Electrolytes

Specific adsorption: Molecular dynamics simulations of the imidazolium‐based ionic liquid/graphite electrode interface illustrate the effects of specific adsorption of the imidazolium cation on both differential capacitance and electric double‐layer structure due to the π‐stacking interaction betwee...

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Bibliographic Details
Published in:Chemphyschem 2012-05, Vol.13 (7), p.1671-1676
Main Authors: Si, Xiujuan, Li, Shu, Wang, Yonglong, Ye, Shihai, Yan, Tianying
Format: Article
Language:English
Subjects:
adsorption
capacitance
Chemistry
electric double layer
Exact sciences and technology
General and physical chemistry
ionic liquids
molecular dynamics simulations
Solid-liquid interface
Solutions
Solvation. Solvent properties
Surface physical chemistry
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Summary:Specific adsorption: Molecular dynamics simulations of the imidazolium‐based ionic liquid/graphite electrode interface illustrate the effects of specific adsorption of the imidazolium cation on both differential capacitance and electric double‐layer structure due to the π‐stacking interaction between the imidazolium cation and the graphite surface.
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.201200013