The First Borosulfate K5[B(SO4)4]

The first of its kind: K5[B(SO4)4], the first example of a borosulfate, comprises non‐condensed [B(SO4)4]5− anions in which the boron atoms are tetrahedrally coordinated to sulfate tetrahedra (see picture; B brown, O red, S yellow). The compound, which crystallizes in a polar space group, was invest...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2012-06, Vol.51 (25), p.6255-6257
Main Authors: Höppe, Henning A., Kazmierczak, Karolina, Daub, Michael, Förg, Katharina, Fuchs, Franziska, Hillebrecht, Harald
Format: Article
Language:English
Subjects:
borosulfates
potassium
structure elucidation
sulfates
sulfur
Online Access:Get full text
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Summary:The first of its kind: K5[B(SO4)4], the first example of a borosulfate, comprises non‐condensed [B(SO4)4]5− anions in which the boron atoms are tetrahedrally coordinated to sulfate tetrahedra (see picture; B brown, O red, S yellow). The compound, which crystallizes in a polar space group, was investigated by X‐ray diffraction, vibrational spectroscopy, and calculations.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201109237