Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes

Transition metal complexes fall under the classification of open shell d-block elements of the periodic table. A study investigated the advantages of two-coordinate complexes that demonstrate high anisotropy and possess useful magnetic properties via first order orbital magnetic event stemming from...

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Bibliographic Details
Published in:Chemical reviews 2012-06, Vol.112 (6), p.3482-3507
Main Author: Power, Philip P
Format: Article
Language:English
Subjects:
Atoms & subatomic particles
Chemistry
Electrons
Metals
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Summary:Transition metal complexes fall under the classification of open shell d-block elements of the periodic table. A study investigated the advantages of two-coordinate complexes that demonstrate high anisotropy and possess useful magnetic properties via first order orbital magnetic event stemming from odd numbers of electrons.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr2004647