Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for a Mixed-Metal System

Sandwich time! The mixed‐metal triangular‐trinuclear sandwich complexes of Pd2Pt and PdPt2 were selectively synthesized. The Pd2Pt and PdPt2 triangles in a cycloheptatrienyl sandwich framework were identified by 31P NMR analyses of the tris‐triphenylphosphine complexes (see scheme).

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Published in:Chemistry : a European journal 2012-07, Vol.18 (29), p.8886-8890
Main Authors: Murahashi, Tetsuro, Usui, Kentaro, Tachibana, Yuki, Kimura, Seita, Ogoshi, Sensuke
Format: Article
Language:English
Subjects:
Chemistry
cluster compounds
palladium
platinum
sandwich complexes
tropylium
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container_issue 29
container_start_page 8886
container_title Chemistry : a European journal
container_volume 18
creator Murahashi, Tetsuro
Usui, Kentaro
Tachibana, Yuki
Kimura, Seita
Ogoshi, Sensuke
description Sandwich time! The mixed‐metal triangular‐trinuclear sandwich complexes of Pd2Pt and PdPt2 were selectively synthesized. The Pd2Pt and PdPt2 triangles in a cycloheptatrienyl sandwich framework were identified by 31P NMR analyses of the tris‐triphenylphosphine complexes (see scheme).
doi_str_mv 10.1002/chem.201201474
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subjects Chemistry
cluster compounds
palladium
platinum
sandwich complexes
tropylium
title Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for a Mixed-Metal System
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