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A Chiral Microporous Polymer Network as Asymmetric Heterogeneous Organocatalyst
Microporous polymer networks, composed of structure‐directing monomers (tectons), can exhibit high permanent surface area and porosity. By choice of suitable tectons various functionalities can be introduced into such networks. Here we introduce chiral BINOL derivatives as novel tectons to generate...
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| Published in: | Advanced synthesis & catalysis 2011-11, Vol.353 (17), p.3101-3106 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c4564-5ec12f5739a297ba69b3ab8b71f2fb87242f629a90a02824b41a1ba3248e93153 |
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| cites | cdi_FETCH-LOGICAL-c4564-5ec12f5739a297ba69b3ab8b71f2fb87242f629a90a02824b41a1ba3248e93153 |
| container_end_page | 3106 |
| container_issue | 17 |
| container_start_page | 3101 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 353 |
| creator | Bleschke, Christian Schmidt, Johannes Kundu, Dipti S. Blechert, Siegfried Thomas, Arne |
| description | Microporous polymer networks, composed of structure‐directing monomers (tectons), can exhibit high permanent surface area and porosity. By choice of suitable tectons various functionalities can be introduced into such networks. Here we introduce chiral BINOL derivatives as novel tectons to generate microporosity in polymer networks. The use of such monomers enables the formation of networks composed solely out of enantiomerically pure compounds. This porous network can be used as a heterogeneous organocatalyst in asymmetric reactions and gives higher enantioselectivty than the homogeneous reaction. |
| doi_str_mv | 10.1002/adsc.201100674 |
| format | article |
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By choice of suitable tectons various functionalities can be introduced into such networks. Here we introduce chiral BINOL derivatives as novel tectons to generate microporosity in polymer networks. The use of such monomers enables the formation of networks composed solely out of enantiomerically pure compounds. This porous network can be used as a heterogeneous organocatalyst in asymmetric reactions and gives higher enantioselectivty than the homogeneous reaction.</description><identifier>ISSN: 1615-4150</identifier><identifier>ISSN: 1615-4169</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201100674</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>asymmetric organocatalysis ; Asymmetry ; Catalysis ; Catalysts: preparations and properties ; Catalytic reactions ; Chemistry ; Condensed benzenic and aromatic compounds ; Derivatives ; Exact sciences and technology ; General and physical chemistry ; heterogeneous asymmetric catalysis ; Microporosity ; Monomers ; Networks ; Organic chemistry ; polymer networks ; Porosity ; porous polymers ; Preparations and properties ; Surface area ; Synthesis ; Theory of reactions, general kinetics. Catalysis. 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| ispartof | Advanced synthesis & catalysis, 2011-11, Vol.353 (17), p.3101-3106 |
| issn | 1615-4150 1615-4169 1615-4169 |
| language | eng |
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| source | Wiley-Blackwell Read & Publish Collection |
| subjects | asymmetric organocatalysis Asymmetry Catalysis Catalysts: preparations and properties Catalytic reactions Chemistry Condensed benzenic and aromatic compounds Derivatives Exact sciences and technology General and physical chemistry heterogeneous asymmetric catalysis Microporosity Monomers Networks Organic chemistry polymer networks Porosity porous polymers Preparations and properties Surface area Synthesis Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | A Chiral Microporous Polymer Network as Asymmetric Heterogeneous Organocatalyst |
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