Intermolecular Regioselective 1,2-Diamination of Allylic Ethers

Homogeneous palladium catalysis enables a novel intermolecular regioselective diamination of allylic ethers, which offers a convenient entry into 1,2,3‐trisubstituted products. These represent suitable building blocks with differently protected nitrogen atoms for subsequent synthetic application.

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2011-03, Vol.353 (5), p.689-694
Main Authors: Muñiz, Kilian, Kirsch, Jonathan, Chávez, Patricia
Format: Article
Language:English
Subjects:
alkenes
amides
Catalysis
Chemistry
diamines
Ethers
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Nitrogen atoms
Organic chemistry
oxidation
Palladium
Preparations and properties
Synthesis
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Description
Summary:Homogeneous palladium catalysis enables a novel intermolecular regioselective diamination of allylic ethers, which offers a convenient entry into 1,2,3‐trisubstituted products. These represent suitable building blocks with differently protected nitrogen atoms for subsequent synthetic application.
ISSN:1615-4150
1615-4169
1615-4169
DOI:10.1002/adsc.201000813