Loading…
Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM
A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers...
Saved in:
Published in: | Polymers for advanced technologies 2011-12, Vol.22 (12), p.2110-2122 |
---|---|
Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693 |
---|---|
cites | cdi_FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693 |
container_end_page | 2122 |
container_issue | 12 |
container_start_page | 2110 |
container_title | Polymers for advanced technologies |
container_volume | 22 |
creator | Lee, Rong-Ho Syu, Jhih-Yang Huang, Jian-Lun |
description | A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers as the electron donor, and a fullerene derivative, (6,6)‐phenyl‐C61‐butyric acid methyl ester (PCBM), as the electron acceptor. The crosslinkable maleimide polymers underwent crosslinking reaction at the side‐chain vinyl groups upon the thermal treatment with or without the addition of initiator, azobisisobutyronitrile (AIBN). Better photovoltaic (PV) performances were obtained for the PSCs based on the polymer crosslinking without using initiator, whereas poorer PV performances were observed for the PSCs based on the polymer crosslinking with the AIBN initiator. In addition, higher operational stability was observed for the crosslinked polymer based solar cell as compared to the solar cell based on the un‐crosslinked polymer. The photo‐physical and PV properties of the cross‐linked maleimide polymers/PCBM based PSCs are discussed in detail as the morphology and crosslinking density of the polymers are taken into account. Copyright © 2010 John Wiley & Sons, Ltd. |
doi_str_mv | 10.1002/pat.1730 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1031293691</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1031293691</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693</originalsourceid><addsrcrecordid>eNp1kE1PwkAQhhujiYgm_oQ9einuR9ulR0BFBZUDRm-bbTuVlW237hYUf72tGIwHTzOZeWaS5_W8U4J7BGN6Xsm6RzjDe16H4Dj2Sdgn-20fUJ-TgB96R869YtzsYt7xPmcLU5u10bVUKaqsqcDWChwyOaoXgCqjNwVY5IyWFqWgtUOpKSqrnCpfUGqNc1qVS8hQITWoQmW7I4dkmaF8pTVYKMHPwKq1rNUa0Gw0vDv2DnKpHZz81K73eHU5H13704fxzWgw9VPGOfZl0KdMSh5GIeMsSSmL4jyOKE1kwhKgjMeZBBJmlMs8y1nQjLMozKMAGCdRzLre2fZvY_e2AleLQrnWRJZgVk4QzAiNm6_kF_32spCLRrSQdtNAoo1XNPGKNt4G9bfou9Kw-ZcTs8H8L69cDR87XtqliDjjoXi6H4twNJnc0ouheGZfY8uNfQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1031293691</pqid></control><display><type>article</type><title>Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM</title><source>Wiley</source><creator>Lee, Rong-Ho ; Syu, Jhih-Yang ; Huang, Jian-Lun</creator><creatorcontrib>Lee, Rong-Ho ; Syu, Jhih-Yang ; Huang, Jian-Lun</creatorcontrib><description>A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers as the electron donor, and a fullerene derivative, (6,6)‐phenyl‐C61‐butyric acid methyl ester (PCBM), as the electron acceptor. The crosslinkable maleimide polymers underwent crosslinking reaction at the side‐chain vinyl groups upon the thermal treatment with or without the addition of initiator, azobisisobutyronitrile (AIBN). Better photovoltaic (PV) performances were obtained for the PSCs based on the polymer crosslinking without using initiator, whereas poorer PV performances were observed for the PSCs based on the polymer crosslinking with the AIBN initiator. In addition, higher operational stability was observed for the crosslinked polymer based solar cell as compared to the solar cell based on the un‐crosslinked polymer. The photo‐physical and PV properties of the cross‐linked maleimide polymers/PCBM based PSCs are discussed in detail as the morphology and crosslinking density of the polymers are taken into account. Copyright © 2010 John Wiley & Sons, Ltd.</description><identifier>ISSN: 1042-7147</identifier><identifier>ISSN: 1099-1581</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.1730</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>cross-linked conjugated polymer ; Crosslinking ; Density ; Derivatives ; Esters ; Initiators ; Interpenetrating networks ; maleimide polymer ; Photovoltaic cells ; photovoltaic property ; polymer solar cell ; Solar cells</subject><ispartof>Polymers for advanced technologies, 2011-12, Vol.22 (12), p.2110-2122</ispartof><rights>Copyright © 2010 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693</citedby><cites>FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lee, Rong-Ho</creatorcontrib><creatorcontrib>Syu, Jhih-Yang</creatorcontrib><creatorcontrib>Huang, Jian-Lun</creatorcontrib><title>Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM</title><title>Polymers for advanced technologies</title><addtitle>Polym. Adv. Technol</addtitle><description>A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers as the electron donor, and a fullerene derivative, (6,6)‐phenyl‐C61‐butyric acid methyl ester (PCBM), as the electron acceptor. The crosslinkable maleimide polymers underwent crosslinking reaction at the side‐chain vinyl groups upon the thermal treatment with or without the addition of initiator, azobisisobutyronitrile (AIBN). Better photovoltaic (PV) performances were obtained for the PSCs based on the polymer crosslinking without using initiator, whereas poorer PV performances were observed for the PSCs based on the polymer crosslinking with the AIBN initiator. In addition, higher operational stability was observed for the crosslinked polymer based solar cell as compared to the solar cell based on the un‐crosslinked polymer. The photo‐physical and PV properties of the cross‐linked maleimide polymers/PCBM based PSCs are discussed in detail as the morphology and crosslinking density of the polymers are taken into account. Copyright © 2010 John Wiley & Sons, Ltd.</description><subject>cross-linked conjugated polymer</subject><subject>Crosslinking</subject><subject>Density</subject><subject>Derivatives</subject><subject>Esters</subject><subject>Initiators</subject><subject>Interpenetrating networks</subject><subject>maleimide polymer</subject><subject>Photovoltaic cells</subject><subject>photovoltaic property</subject><subject>polymer solar cell</subject><subject>Solar cells</subject><issn>1042-7147</issn><issn>1099-1581</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp1kE1PwkAQhhujiYgm_oQ9einuR9ulR0BFBZUDRm-bbTuVlW237hYUf72tGIwHTzOZeWaS5_W8U4J7BGN6Xsm6RzjDe16H4Dj2Sdgn-20fUJ-TgB96R869YtzsYt7xPmcLU5u10bVUKaqsqcDWChwyOaoXgCqjNwVY5IyWFqWgtUOpKSqrnCpfUGqNc1qVS8hQITWoQmW7I4dkmaF8pTVYKMHPwKq1rNUa0Gw0vDv2DnKpHZz81K73eHU5H13704fxzWgw9VPGOfZl0KdMSh5GIeMsSSmL4jyOKE1kwhKgjMeZBBJmlMs8y1nQjLMozKMAGCdRzLre2fZvY_e2AleLQrnWRJZgVk4QzAiNm6_kF_32spCLRrSQdtNAoo1XNPGKNt4G9bfou9Kw-ZcTs8H8L69cDR87XtqliDjjoXi6H4twNJnc0ouheGZfY8uNfQ</recordid><startdate>201112</startdate><enddate>201112</enddate><creator>Lee, Rong-Ho</creator><creator>Syu, Jhih-Yang</creator><creator>Huang, Jian-Lun</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201112</creationdate><title>Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM</title><author>Lee, Rong-Ho ; Syu, Jhih-Yang ; Huang, Jian-Lun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>cross-linked conjugated polymer</topic><topic>Crosslinking</topic><topic>Density</topic><topic>Derivatives</topic><topic>Esters</topic><topic>Initiators</topic><topic>Interpenetrating networks</topic><topic>maleimide polymer</topic><topic>Photovoltaic cells</topic><topic>photovoltaic property</topic><topic>polymer solar cell</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Rong-Ho</creatorcontrib><creatorcontrib>Syu, Jhih-Yang</creatorcontrib><creatorcontrib>Huang, Jian-Lun</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Rong-Ho</au><au>Syu, Jhih-Yang</au><au>Huang, Jian-Lun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM</atitle><jtitle>Polymers for advanced technologies</jtitle><addtitle>Polym. Adv. Technol</addtitle><date>2011-12</date><risdate>2011</risdate><volume>22</volume><issue>12</issue><spage>2110</spage><epage>2122</epage><pages>2110-2122</pages><issn>1042-7147</issn><issn>1099-1581</issn><eissn>1099-1581</eissn><abstract>A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers as the electron donor, and a fullerene derivative, (6,6)‐phenyl‐C61‐butyric acid methyl ester (PCBM), as the electron acceptor. The crosslinkable maleimide polymers underwent crosslinking reaction at the side‐chain vinyl groups upon the thermal treatment with or without the addition of initiator, azobisisobutyronitrile (AIBN). Better photovoltaic (PV) performances were obtained for the PSCs based on the polymer crosslinking without using initiator, whereas poorer PV performances were observed for the PSCs based on the polymer crosslinking with the AIBN initiator. In addition, higher operational stability was observed for the crosslinked polymer based solar cell as compared to the solar cell based on the un‐crosslinked polymer. The photo‐physical and PV properties of the cross‐linked maleimide polymers/PCBM based PSCs are discussed in detail as the morphology and crosslinking density of the polymers are taken into account. Copyright © 2010 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pat.1730</doi><tpages>13</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1042-7147 |
ispartof | Polymers for advanced technologies, 2011-12, Vol.22 (12), p.2110-2122 |
issn | 1042-7147 1099-1581 1099-1581 |
language | eng |
recordid | cdi_proquest_miscellaneous_1031293691 |
source | Wiley |
subjects | cross-linked conjugated polymer Crosslinking Density Derivatives Esters Initiators Interpenetrating networks maleimide polymer Photovoltaic cells photovoltaic property polymer solar cell Solar cells |
title | Photovoltaic properties of the polymer solar cells comprising crosslinked maleimide polymers and fullerene-derivative PCBM |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T18%3A25%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photovoltaic%20properties%20of%20the%20polymer%20solar%20cells%20comprising%20crosslinked%20maleimide%20polymers%20and%20fullerene-derivative%20PCBM&rft.jtitle=Polymers%20for%20advanced%20technologies&rft.au=Lee,%20Rong-Ho&rft.date=2011-12&rft.volume=22&rft.issue=12&rft.spage=2110&rft.epage=2122&rft.pages=2110-2122&rft.issn=1042-7147&rft.eissn=1099-1581&rft_id=info:doi/10.1002/pat.1730&rft_dat=%3Cproquest_cross%3E1031293691%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3770-a4823aa7565373bc2369f9622bab3be2379dae15d27afdf34ab3d65f64e371693%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1031293691&rft_id=info:pmid/&rfr_iscdi=true |