Recent Advances in Catalytic Enantioselective Fluorination Reactions

Since the incorporation of fluorine into biologically active compounds often enhances the properties of the parent compounds, there is a considerable demand for efficient enantioselective fluorination reactions. Over the past decade, a range of metal‐catalyzed and organocatalyzed fluorination reacti...

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Published in:Advanced synthesis & catalysis 2010-11, Vol.352 (16), p.2708-2732
Main Authors: Lectard, Sylvain, Hamashima, Yoshitaka, Sodeoka, Mikiko
Format: Article
Language:English
Subjects:
asymmetric catalysis
Catalysis
Catalysts
Demand
electrophilic fluorination
Fluorination
Fluorine
fluorine chemistry
Marketing
nucleophilic fluorination
organocatalysis
organometallic catalysis
Parents
Synthesis
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description Since the incorporation of fluorine into biologically active compounds often enhances the properties of the parent compounds, there is a considerable demand for efficient enantioselective fluorination reactions. Over the past decade, a range of metal‐catalyzed and organocatalyzed fluorination reactions has been developed. Nowadays, fluorine can be catalytically introduced into many compounds in good yield and with high enantioselectivity, and the scope of these reactions is broad. Herein, we review recent progress in the field of catalytic enantioselective fluorination reactions, including their scope and mechanism.
doi_str_mv 10.1002/adsc.201000624
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subjects asymmetric catalysis
Catalysis
Catalysts
Demand
electrophilic fluorination
Fluorination
Fluorine
fluorine chemistry
Marketing
nucleophilic fluorination
organocatalysis
organometallic catalysis
Parents
Synthesis
title Recent Advances in Catalytic Enantioselective Fluorination Reactions
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