Loading…
Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction
An efficient , asymmetric, one‐pot synthesis of a novel tetracyclic ring system incorporating both chroman and bicyclo[2.2.2]octane structural units was established through sequential reaction of nitroolefin enoates and α,β‐unsaturated ketones. Six stereogenic centers including two quaternary stereo...
Saved in:
| Published in: | Advanced synthesis & catalysis 2011-11, Vol.353 (16), p.2960-2965 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3 |
| container_end_page | 2965 |
| container_issue | 16 |
| container_start_page | 2960 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 353 |
| creator | Yu, De-Feng Wang, Yao Xu, Peng-Fei |
| description | An efficient , asymmetric, one‐pot synthesis of a novel tetracyclic ring system incorporating both chroman and bicyclo[2.2.2]octane structural units was established through sequential reaction of nitroolefin enoates and α,β‐unsaturated ketones. Six stereogenic centers including two quaternary stereocenters were formed with excellent diastereo‐ and enantioselectivity. |
| doi_str_mv | 10.1002/adsc.201100332 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1031305523</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1031305523</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3</originalsourceid><addsrcrecordid>eNqFkE1vEzEQhlcIJErhytkXJC6b-mO9zh6r9IOiKqnSIiQu1sSeLQbHLrYb2H-Pq1QRN04zIz3vM9LbNO8ZnTFK-QnYbGacsnoIwV80R6xnsu1YP7w87JK-bt7k_INSpuZKHTXlzEEumDC2BIIl5wFCcTGjR1PcDsntFMp3zC6TOBIgy7hDT-6wJDCT8c6QtQv3laqSLdk5qBaySvcQooECfioVWQVsb2Iha4QqjeFt82oEn_Hd8zxuvlyc3y0-tdery6vF6XVrxEB5i_OOg2IKRslxg2yjqGSgFOOUW9rTsR8VtYPhYrTC9oYJubGcWZhTkB234rj5uPc-pPjrEXPRW5cNeg8B42PWjAomqJRcVHS2R02KOScc9UNyW0hThfRTvfqpXn2otwY-PLshG_BjgmBcPqR4p1Q39F3lhj3323mc_mPVp2e3i39_tPusq-3-OWQh_dS9Ekrqr8tLve74zfD521JfiL98_5s9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1031305523</pqid></control><display><type>article</type><title>Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction</title><source>Wiley:Jisc Collections:Wiley Read and Publish Open Access 2024-2025 (reading list)</source><creator>Yu, De-Feng ; Wang, Yao ; Xu, Peng-Fei</creator><creatorcontrib>Yu, De-Feng ; Wang, Yao ; Xu, Peng-Fei</creatorcontrib><description>An efficient , asymmetric, one‐pot synthesis of a novel tetracyclic ring system incorporating both chroman and bicyclo[2.2.2]octane structural units was established through sequential reaction of nitroolefin enoates and α,β‐unsaturated ketones. Six stereogenic centers including two quaternary stereocenters were formed with excellent diastereo‐ and enantioselectivity.</description><identifier>ISSN: 1615-4150</identifier><identifier>ISSN: 1615-4169</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201100332</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alicyclic compounds ; Alicyclic compounds, terpenoids, prostaglandins, steroids ; Asymmetry ; bicyclo[2.2.2]octanes ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; chromans ; Exact sciences and technology ; General and physical chemistry ; Heterocyclic compounds ; Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives ; Ketones ; one-pot reaction ; Organic chemistry ; organocatalysis ; Preparations and properties ; Synthesis ; tetracyclic ring systems ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Advanced synthesis & catalysis, 2011-11, Vol.353 (16), p.2960-2965</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3</citedby><cites>FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24774964$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yu, De-Feng</creatorcontrib><creatorcontrib>Wang, Yao</creatorcontrib><creatorcontrib>Xu, Peng-Fei</creatorcontrib><title>Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction</title><title>Advanced synthesis & catalysis</title><addtitle>Adv. Synth. Catal</addtitle><description>An efficient , asymmetric, one‐pot synthesis of a novel tetracyclic ring system incorporating both chroman and bicyclo[2.2.2]octane structural units was established through sequential reaction of nitroolefin enoates and α,β‐unsaturated ketones. Six stereogenic centers including two quaternary stereocenters were formed with excellent diastereo‐ and enantioselectivity.</description><subject>Alicyclic compounds</subject><subject>Alicyclic compounds, terpenoids, prostaglandins, steroids</subject><subject>Asymmetry</subject><subject>bicyclo[2.2.2]octanes</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>chromans</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives</subject><subject>Ketones</subject><subject>one-pot reaction</subject><subject>Organic chemistry</subject><subject>organocatalysis</subject><subject>Preparations and properties</subject><subject>Synthesis</subject><subject>tetracyclic ring systems</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>1615-4150</issn><issn>1615-4169</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkE1vEzEQhlcIJErhytkXJC6b-mO9zh6r9IOiKqnSIiQu1sSeLQbHLrYb2H-Pq1QRN04zIz3vM9LbNO8ZnTFK-QnYbGacsnoIwV80R6xnsu1YP7w87JK-bt7k_INSpuZKHTXlzEEumDC2BIIl5wFCcTGjR1PcDsntFMp3zC6TOBIgy7hDT-6wJDCT8c6QtQv3laqSLdk5qBaySvcQooECfioVWQVsb2Iha4QqjeFt82oEn_Hd8zxuvlyc3y0-tdery6vF6XVrxEB5i_OOg2IKRslxg2yjqGSgFOOUW9rTsR8VtYPhYrTC9oYJubGcWZhTkB234rj5uPc-pPjrEXPRW5cNeg8B42PWjAomqJRcVHS2R02KOScc9UNyW0hThfRTvfqpXn2otwY-PLshG_BjgmBcPqR4p1Q39F3lhj3323mc_mPVp2e3i39_tPusq-3-OWQh_dS9Ekrqr8tLve74zfD521JfiL98_5s9</recordid><startdate>201111</startdate><enddate>201111</enddate><creator>Yu, De-Feng</creator><creator>Wang, Yao</creator><creator>Xu, Peng-Fei</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>201111</creationdate><title>Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction</title><author>Yu, De-Feng ; Wang, Yao ; Xu, Peng-Fei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alicyclic compounds</topic><topic>Alicyclic compounds, terpenoids, prostaglandins, steroids</topic><topic>Asymmetry</topic><topic>bicyclo[2.2.2]octanes</topic><topic>Catalysis</topic><topic>Catalysts: preparations and properties</topic><topic>Chemistry</topic><topic>chromans</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Heterocyclic compounds</topic><topic>Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives</topic><topic>Ketones</topic><topic>one-pot reaction</topic><topic>Organic chemistry</topic><topic>organocatalysis</topic><topic>Preparations and properties</topic><topic>Synthesis</topic><topic>tetracyclic ring systems</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, De-Feng</creatorcontrib><creatorcontrib>Wang, Yao</creatorcontrib><creatorcontrib>Xu, Peng-Fei</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, De-Feng</au><au>Wang, Yao</au><au>Xu, Peng-Fei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction</atitle><jtitle>Advanced synthesis & catalysis</jtitle><addtitle>Adv. Synth. Catal</addtitle><date>2011-11</date><risdate>2011</risdate><volume>353</volume><issue>16</issue><spage>2960</spage><epage>2965</epage><pages>2960-2965</pages><issn>1615-4150</issn><issn>1615-4169</issn><eissn>1615-4169</eissn><abstract>An efficient , asymmetric, one‐pot synthesis of a novel tetracyclic ring system incorporating both chroman and bicyclo[2.2.2]octane structural units was established through sequential reaction of nitroolefin enoates and α,β‐unsaturated ketones. Six stereogenic centers including two quaternary stereocenters were formed with excellent diastereo‐ and enantioselectivity.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/adsc.201100332</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1615-4150 |
| ispartof | Advanced synthesis & catalysis, 2011-11, Vol.353 (16), p.2960-2965 |
| issn | 1615-4150 1615-4169 1615-4169 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1031305523 |
| source | Wiley:Jisc Collections:Wiley Read and Publish Open Access 2024-2025 (reading list) |
| subjects | Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Asymmetry bicyclo[2.2.2]octanes Catalysis Catalysts: preparations and properties Chemistry chromans Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Ketones one-pot reaction Organic chemistry organocatalysis Preparations and properties Synthesis tetracyclic ring systems Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Diastereo- and Enantioselective Synthesis of a Novel Tetracyclic Ring System via an Organocatalytic One-Pot Reaction |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-23T02%3A27%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Diastereo-%20and%20Enantioselective%20Synthesis%20of%20a%20Novel%20Tetracyclic%20Ring%20System%20via%20an%20Organocatalytic%20One-Pot%20Reaction&rft.jtitle=Advanced%20synthesis%20&%20catalysis&rft.au=Yu,%20De-Feng&rft.date=2011-11&rft.volume=353&rft.issue=16&rft.spage=2960&rft.epage=2965&rft.pages=2960-2965&rft.issn=1615-4150&rft.eissn=1615-4169&rft_id=info:doi/10.1002/adsc.201100332&rft_dat=%3Cproquest_cross%3E1031305523%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3902-e842a717af52ebe1b7051a771202d060f6f70d9c23fd3d6c135bd21da80a542d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1031305523&rft_id=info:pmid/&rfr_iscdi=true |