Synthesis of nickel oxide nanoparticles using pulsed laser ablation in liquids and their optical characterization

• Published in: Applied surface science 2012-07, Vol.258 (18), p.6982-6986
• Main Authors: Gondal, M.A., Saleh, Tawfik A., Drmosh, Q.A.
• Format: Article
• Language: English
• Subjects: Band spectra; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Laser ablation; Metal oxides; Nanomaterials; Nanoparticles; Nanostructure; Nickel oxides; Nickle oxide; Optical properties; Physics; Pulsed laser ablation; Pulsed lasers; Scanning electron microscopy; Synthesis
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2012.03.147

► NiO nanoparticles were prepared by pulsed laser ablation technique. ► The structural properties were investigated by XRD, FE-SEM, EDX spectroscopy. ► Optical properties were studied by HR spectrofluorometery, UV–Vis and FTIR spectroscopy. ► XRD analysis confirms lattice parameter=0.4203nm and 8nm grain size. ► Photoluminescence emission spectrum showed strong peak at 3.62eV attributed to band edge transition. Nanomaterials are of great interest due to their applications in many fields. The structural and efficacy of nano-materials depend strongly on the method applied for their synthesis. In this work, nanosized nickel oxide (NiO) particles were prepared by pulsed laser ablation (PLA) technique in 3% H2O2 aqueous solution The structural and optical properties of the NiO were investigated by X-ray diffractometer (XRD), field emission scanning electron microscope (FE-SEM), energy dispersive X-ray spectroscope (EDX), UV–Vis spectroscopy and Fourier-transform infrared spectroscopy (FT-IR). XRD analysis confirms that the phase is pure nickel oxide with lattice parameter=0.42033nm and 8nm grain size while photoluminescence emission spectrum showed strong peak at 3.62eV attributed to the band edge transition. FT-IR spectra depicts a strong band at ∼450cm−1 which corresponds to the bending vibration of Ni–O bond. This work demonstrates that PLA is an effective method to control the size, impurity and minimal chemical waste generation which is the major problem with other wet chemical methods.