Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis

Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (70), p.8766-8768
Main Authors: Zhang, Teng, Song, Feijie, Lin, Wenbin
Format: Article
Language:English
Subjects:
Catalysis
Cobalt - chemistry
Coordination Complexes - chemistry
Crystallography, X-Ray
Dicarboxylic Acids - chemistry
Ethylenediamines - chemistry
Furans - chemistry
Ligands
Magnetic Resonance Spectroscopy
Models, Molecular
Stereoisomerism
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Description
Summary:Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc34033j