Di-μ-azido-κ(4)N:N-bis-({2-[(3-amino-2,2-dimethyl-prop-yl)imino-meth-yl]-6-meth-oxy-phenolato-1κ(3)N,N',O(1)}copper(II))

The complete mol-ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tri...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-07, Vol.68 (Pt 7), p.m993-m994
Main Authors: Ghaemi, Akbar, Rayati, Saeed, Fayyazi, Kazem, Ng, Seik Weng, Tiekink, Edward R T
Format: Article
Language:English
Online Access:Get full text
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Summary:The complete mol-ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti-cipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific inter-molecular inter-actions are noted in the crystal packing, but the amine H atoms form intra-molecular N-H⋯O(oxide)/N(azide) hydrogen bonds.
ISSN:1600-5368
DOI:10.1107/S1600536812028954