Highly stereoselective Ru(II)-Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

The Ru(II)-Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereosel...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-08, Vol.48 (62), p.7750-7752
Main Authors: Chanthamath, Soda, Phomkeona, Kesiny, Shibatomi, Kazutaka, Iwasa, Seiji
Format: Article
Language:English
Subjects:
Alkenes - chemistry
Asymmetry
Catalysis
Catalysts
Cyclopropane
Cyclopropanes - chemistry
Magnetic Resonance Spectroscopy
Molecular Structure
Olefins
Oxazoles - chemistry
Ruthenium - chemistry
Stereoisomerism
Succinimides - chemistry
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Summary:The Ru(II)-Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereoselectivity and enantioselectivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32706f