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Upscaling potential of the CVD stacking growth method to produce dimensionally-controlled and catalyst-free multi-walled carbon nanotubes
Multi-walled CNTs (MWCNTs) with structural characteristics optimised for bio-applications have been produced using a catalyst-supported chemical vapour deposition (CVD) method. The upscale potential of the process was demonstrated by combining classical semi-continuous and stacked-growth modes. The...
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Published in: | Carbon (New York) 2012-08, Vol.50 (10), p.3585-3606 |
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creator | Mata, D. Silva, R.M. Fernandes, A.J.S. Oliveira, F.J. Costa, P.M.F.J. Silva, R.F. |
description | Multi-walled CNTs (MWCNTs) with structural characteristics optimised for bio-applications have been produced using a catalyst-supported chemical vapour deposition (CVD) method. The upscale potential of the process was demonstrated by combining classical semi-continuous and stacked-growth modes. The vertically aligned MWCNT films thus obtained were multi-layered with five continuous strata of well-structured nanotubes. Following gentle disentanglement, the stacks were converted to individual MWCNTs with short dimensions (a final length and diameter of ∼1.2μm and ∼12nm) and almost catalyst-free ( |
doi_str_mv | 10.1016/j.carbon.2012.03.030 |
format | article |
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These constitute key steps towards the mass production of MWCNTs with low toxicological risks, an essential prerequisite for biomedical applications.</description><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical vapor deposition</subject><subject>Chemistry</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>General and physical chemistry</subject><subject>Materials science</subject><subject>Multi wall carbon nanotubes</subject><subject>Physics</subject><subject>Purification</subject><subject>Specific materials</subject><subject>Stacking</subject><subject>Strata</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mata, D.</creatorcontrib><creatorcontrib>Silva, R.M.</creatorcontrib><creatorcontrib>Fernandes, A.J.S.</creatorcontrib><creatorcontrib>Oliveira, F.J.</creatorcontrib><creatorcontrib>Costa, P.M.F.J.</creatorcontrib><creatorcontrib>Silva, R.F.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mata, D.</au><au>Silva, R.M.</au><au>Fernandes, A.J.S.</au><au>Oliveira, F.J.</au><au>Costa, P.M.F.J.</au><au>Silva, R.F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Upscaling potential of the CVD stacking growth method to produce dimensionally-controlled and catalyst-free multi-walled carbon nanotubes</atitle><jtitle>Carbon (New York)</jtitle><date>2012-08-01</date><risdate>2012</risdate><volume>50</volume><issue>10</issue><spage>3585</spage><epage>3606</epage><pages>3585-3606</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>Multi-walled CNTs (MWCNTs) with structural characteristics optimised for bio-applications have been produced using a catalyst-supported chemical vapour deposition (CVD) method. 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subjects | Carbon Catalysis Catalysts Chemical vapor deposition Chemistry Cross-disciplinary physics: materials science rheology Exact sciences and technology Fullerenes and related materials diamonds, graphite General and physical chemistry Materials science Multi wall carbon nanotubes Physics Purification Specific materials Stacking Strata Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | Upscaling potential of the CVD stacking growth method to produce dimensionally-controlled and catalyst-free multi-walled carbon nanotubes |
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