Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant

The stable pyridinium salt of o-iodoxybenzoic acid (PIBX) that is easy to obtain can serve as a convenient substitute of IBX as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents (DMF, DMSO), and pr...

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Bibliographic Details
Published in:Mendeleev communications 2012-05, Vol.22 (3), p.129-131
Main Authors: Kumanyaev, Ivan M., Lapitskaya, Margarita A., Vasiljeva, Ljudmila L., Pivnitsky, Kasimir K.
Format: Article
Language:English
Subjects:
Aldehydes
Equivalence
Ketones
Oxidants
Oxidation rate
Oxidizing agents
Solubility
Solvents
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Summary:The stable pyridinium salt of o-iodoxybenzoic acid (PIBX) that is easy to obtain can serve as a convenient substitute of IBX as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents (DMF, DMSO), and provides higher oxidation rate in THF due to better solubility.
ISSN:0959-9436
DOI:10.1016/j.mencom.2012.05.004