XPS study on the correlation of magnetic properties and site occupancy of Al doped SrFe12O19

• Published in: Journal of alloys and compounds 2012-08, Vol.532, p.114-120
• Main Authors: Sahu, Ranjan K., Mohanta, O., Pramanik, A.K.
• Format: Article
• Language: English
• Subjects: Aluminum; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Correlation analysis; Domain effects, magnetization curves, and hysteresis; Doping; Exact sciences and technology; Iron; Magnetic moment; Magnetic properties; Magnetic properties and materials; Magnetization; Magnetization curves, magnetization reversal, hysteresis, barkhausen and related effects; Microwave-assisted chemical synthesis; Permanent magnets; Photoelectron spectroscopies; Physics; X-ray photoelectron spectroscopy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2011.11.049

The correlation of Fe 3s XPS spectrum and the magnetic properties of SrFe12−xAlxO19 show that the intensity of majority peak decreased with the doping of Al ion and the spectral features are associated with the magnetic moment. [Display omitted] ► The coercivity of SrFe12O19 increased from 5420Oe to 7340Oe by doping of 10% Al ion. ► The correlation of XPS and magnetic data suggests that the majority peak intensity of Fe 3s XPS spectrum is associated with the magnetization value, and can be used as a spectroscopic diagnostic tool to comprehend the doping effect of Al ion on the magnetic moment of spin up and spin down sublattice of hexaferrite. ► The XPS Fe 3s and Fe 2p data indicate the Al ions occupy the 2a site of the crystal structure up to x=1.2, and beyond the dopant ions distribute at other occupation sites. We have performed an X-ray photoelectron spectroscopy (XPS) study of SrFe12−xAlxO19 (0≤x≤2.4), and the results have been correlated to the magnetic properties measured using VSM technique. The coercivity of the parent compound increased from 5420Oe to 7340Oe with increasing the doping concentration of Al ions up to x=1.2. The XPS data of Fe 3s spectrum show that the intensity of majority peak decreased with the doping of Al ion and it is associated with the magnetic moment. The XPS analysis of Fe 2p data in conjugation with the Fe 3s data suggests that the Al ions occupy the 2a site of the crystal structure up to x=1.2, and beyond the dopant ions distribute at other occupation sites. The observed correlation between the spectral features of Fe 3s spectrum and the magnetic data suggests that XPS technique can also be used as a spectroscopic diagnostic tool to comprehend the influence of doping ion on the magnetic moment of spin up and spin down sublattice of ferrimagnetic structure.